01-05-21 - SR.N-SUPER CHAINA - Jee-Adv - UTA-1 - SYLLABUS: Sec: OSR - IIT - N-SC Date: 01-05-21 Time: 03:00 Hrs Max. Marks: 180

Sec: OSR.
IIT_N-SC Date: 01-05-21

Time: 03:00 Hrs Max. Marks:
180
Name of the Student: ___________________ H.T. NO:
01-05-21_SR.N-SUPER CHAINA_Jee-Adv_UTA-1_SYLLABUS
PHYSICS: Kinematics, Laws of Motion, Friction, Work Power Energy, Circular

Motion, Conservation of Momentum, Rotational Mechanics
CHEMISTRY: Stoichiometry, Atomic structure
Hydrocarbons, Benzene
Periodic classification, Chemical bonding, Group-14
MATHEMATICS : Logarithms, Quadratic equations, Sequence & Series, Complex
numbers
Narayana IIT Academy 01-05-21_OSR.IIT_N-SC_ JEE-Adv_UTA-1_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30
Total 20 60
CHEMISTRY:
Total 20 60
MATHS:
Total 20 60
SR.IIT_N-SC/ N-C Page. No. 2
Strive for Progress, Not perfection.

PHYSICS Max Marks : 60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D)
out of which ONE or MORE are correct.
1. An aero plane flies along straight line from A to B with speed v and back again with the
same air speed. There is a steady wind speed w. The distance between A and B is d.
Total time for the round trip
2 vd
A) is if the wind blows along the line AB.
v  w2
2
2d
B) is if the wind blows perpendicular to the line AB.
v2  w 2
C) is always increased by the presence of wind.(Compared with the case, without wind)
D) depend on the direction of wind.
2. As shown in figure pulley is ideal and strings are massless. If mass m of hanging block is
the minimum mass to set the equilibrium of system then – (g = 10 m/s2)
= 37º
= 37º
m
20 kg
µ = 0.5
 = 37º
A) m = 2.5 kg
B) m = 5 kg
C) force applied by 20 kg block on inclined plane is nearly 179 N
D) force applied by 20 kg block on inclined plane is nearly 223 N

3. A rough L-shaped rod is located in a horizontal plane and a sleeve of mass m is inserted
in the rod. The rod is rotated with a constant angular velocity  in the horizontal plane
about the end A. The lengths are shown in figure. The normal reaction and frictional
force acting on the sleeve when it just starts slipping are (µ = coefficient of friction
between rod and sleeve)
A) N = m2l1 B) f = m2l2 C) N = m g 2  4  12 D) f = µN
4. As shown in figure the horizontal surface of block M0 is smooth and its vertical surface is
rough with a coefficient of friction . Then –
m1
smooth
F M0 m2
Rough
Smooth
A) If F = 0 the blocks can not remain stationary

m 2 ( M 0  m1  m 2 ) g
B) For F = , blocks m1 and m2 remain stationary with respect to M0
m1 – m 2
( M 0  m1  m2 ) .m g
C) For F = 2 , blocks m1 and m2 remain stationary with respect to M0
m1
D) The limiting friction between m2 and M0 is independent of F

5. The two blocks A and B of equal mass are initially in contact when released from rest on
the inclined plane. The coefficients of friction between the inclined plane and A and B
are 1 and 2 respectively -
B
A

A) If 1>2, the blocks will always remain in contact
B) If 1<2, the blocks will slide down with different accelerations
C) If 1 >2, the blocks will have a common acceleration 1

(1 + 2)gsin
2
1 2 g
D) If 1 <2, the blocks will have a common acceleration sin 
1   2
6. A ball of mass m is attached with a light string of length  and released from position 1.
The string becomes taut at position 2 and reaches to lowest position 3 –
3g
A) velocity of balljust after string becomes taut is
2
g
B) velocity of ball just after string becomes taut is
2
C) Energy of ball is conserved from position 1 to position 3

D)Energy of ball is not conserved from position 1 to position 3

7. A body moves in a circular path of radius R with deceleration so that at any moment of
time its tangential and normal accelerations are equal in magnitude. At the initial moment
t = 0, the velocity of body is v0 then the velocity of body will be-
v0
A) v  at time t
 v0t 
1  
 R 
B) v  v0 .e  S / R after it has moved S meter
C) v  v0 .e SR after it has moved S meter
v0
D) v  at time t.
2v0t
1
R
8. A ball of mass m hits a wedge of mass '2m' with velocity 'v0' in horizontal direction and
moves in vertically upward direction with velocity 'v0/2'. There is no friction between
wedge and the surface -
v0 m
2m 45°
A) Coefficient of restitution between ball and wedge is 1
3
B) Coefficient of restitution between ball and wedge is
4
5
C) Impulse on wedge due to ball is mv 0
2
D) Impulse on wedge due to surface is mv0

2

9. A uniform bar of length 6a and mass 8m lies on a smooth horizontal table. Two point
masses m and 2m moving in the same horizontal plane with speed 2v and v respectively,
strike the bar (as shown in the figure) and stick to the bar after collision. Denoting
angular velocity (about the centre of mass), total energy and centre of mass velocity by
; E and Vc respectively, we have after collision –
2m
v 3a
a 2a
2v
3
A) Vc = 0 B)  = 3v
C)  = v
D) E  mv 2
5a 5a 5
10. A particle 'P' of mass m is attached to a vertical axis by two string AP & BP of length ''
each. The separation AB = . 'P' rotates around the axis with angular velocity ''. The
tensions in the two strings are T1& T2 –
A) T1 = T2 B) T1 + T2 = m2
C) T1 – T2 = 2mg D) BP will remain taut only if  2g



SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from
0 to 9 (both inclusive).
11. A swimmer jumps from a bridge over a canal and swims 1 km up stream. After that first
km, he passes a floating cork. He continues swimming for half an hour and then turns
around and swims back to the bridge. The swimmer and the cork reach the bridge at the
same time. The swimmer has been swimming at a constant speed with respect to water.
How fast does the water in the canal flow in km/hr.
12. A canon shell moving along a straight line bursts in to two parts. Just after the burst one
part moves with momentum 20 Ns making an angle 300 with the original line of motion.
The minimum momentum of the other part of shell just after the burst is (in multiples of
2 in Ns):
13. Three blocks A, B and C of mass m each are arranged in pulley mass system as shown.
Coefficient of friction between block A and horizontal surface is equal to 0.5 and a
force P acts on 'A' in the direction shown. The value of P/mg so that block 'C' doesn't
move is –
A P
C B
14. Two blocks A and B, each of mass m = 2kg are connected to the ends of an ideal spring
of force constant k = 1000 Nm–1 and this system is placed on rough floor. Coefficient of
friction between these blocks and floor is  = 0.5. Block B is pressed towards left so
that spring gets compressed. Then the initial minimum compression of spring in cm
such that block A leaves contact with the wall when system is released is (g = 10 m/s2)
A B

15. A cube of mass 3kg is kept on a frictionless horizontal surface. The block is given an
impulse so that point ‘A’ acquires velocity 4 m/s in the direction shown. If speed of
point B is 4 2 m/s, K.E. of block (in Joule) minus 10 Joule is -
B A 4 m/s
10 cm
16. A small bead of mass m can move on a smooth circular wire (radius R) under the action
Km
of a force F = directed (r = position of bead from P & K = constant) towards a point
r2
P within the circle at a distance R/2 from the centre. What should be the minimum
velocity (in m/s) of bead at the point of the wire nearest the centre of force (P) so that
k
bead will complete the circle (Take = 8 unit)
3R
17. A wedge of mass M = 2 m0 rests on a smooth horizontal plane. A small block of mass
m0 rests over it at left end A as shown in figure. A sharp impulse is applied on the
block, due to which it starts moving to the right with velocity v0 = 6 m/s. At highest
point of its trajectory, the block collides with a particle of same mass m0 moving
vertically downwards with velocity v = 2 m/s and gets stuck with it. If the combined
mass lands at the end point A of the body of mass M, calculate the value of (l/10) in
cm. Neglect friction, take g = 10 m/s2.
B
20 cm
m0
A
l
18. A point P is located on the rim of wheel of radius r = 0.5 m which rolls without slipping
along a horizontal surface then the total distance traversed by the point P in meters
between two successive moments it touches the surface.

19. The spring of block system lies on a smooth horizontal surface. The free end of the
spring is being pulled towards right with constant speed V0  2 m / s . At t  0sec , the
spring of constant k  100 N / cm is unstretched and the block has a speed 1 m/s to left.
The maximum extension of the spring is(in cm)
20. A homogeneous rod of mass 3 kg is pushed along smooth horizontal surface by a
horizontal force
F = 40 N. If '' (in degree) is the angle for which rod has pure translation motion. Then
( is-
(g = 10m/s2)
F = 40 N 

CHEMISTRY Max Marks : 60
SECTION-I
21. 100 mL of H 2O2 solution having volume strength 11.35 V is mixed with 50 mL of
0.5M KI solution to liberate I 2 gas. All the I 2 gas liberated is trapped to form a 500 mL
solution termed as X. 200 mL of the solution X of I 2 required 50 mL hypo solution for

conversion to I  and S4O62 . Assuming all reactions to undergo 100% completion,
identify the correct option(s).
A) Volume strength of remaining H 2O2 solution will be 6.62 V .
B) Molarity of I 2 in solution X is 0.025 M.
C) Molarity of hypo solution taken is 0.2 M.
D) Moles of tetrathionate ions formed will be 0.01.
22. For the reaction,
MnO2  s   4 HCl  MnCl2  2 H 2O  Cl2 ( g )
261 gm of MnO2 is mixed with 448 liters of HCl gas at 2730 C and 1 atm pressure to
produce products. [ N A  6 1023; Atomic mass of Mn  55, Cl  35.5]
Select the correct statement(s) amongst the following :
A) MnO2 is the limiting reagent.
B) Chlorine gas produced contains 15  1023 molecules.
C) Moles of excess reactant left is 0.5 moles.
D) If % yield of reaction is 50 %, then moles of MnCl2 obtained will be 2.5

23. In which one of the following reaction(s), product(s) given is/are incorrect ?
EtONa in EiOH
(Major)
A) Br
Me Ph Ph
Ph alc. KOH
(Major)
Ph
Me
B) Br
Me Me
Me
NaOEt in EtOH
(Minor) + (Major)
Cl
C)
Conc. H 2SO 4 Ph
Ph
 (Major)
D) OH
1/2
If total energy of electron in H-atom is -1.51 eV and angular part is   sin .cos 
3
24.
 4 
then no. of radial nodes describing the electron is
A) 1 B) 0 C) 2 D) 3
25. Which of the following is/are correct about sheet silicates

A) repeating unit is Si 2O52
B) three oxygens of each tetrahedron are shared
C) two tetrahedrons are present in repeating unit
D) repeating unit is Si 2O53
26. The correct order/s of bond angle is/are
A) PH4  H2O  OF2  SF2 B) PF3  PCl3  PBr3  PI3
C) BF3  CH4  NH3  NF3 D) BF3  BCl3  BBr3  BI3

27. Which of the following would have same magnetic nature whether ‘sp’ mixing is
operative or not
A) C 2 B) B2 C) O 2 D) N2
28.
Which product(s) is/are formed during the above reaction?
29.
  A    B
complete

reductive
ozonolysis
hydrolysis
molecular weight of (A) is greater than that of (B). (A) & (B) are carbon compounds
Which of the following is/are correct
A) (A) & (B) both have same number of sp 2 carbons
B) (B) is glyoxal and (A) methyl glyoxal
C) (A) has both sp 2 & sp3 carbons
D) Difference in molecular weights of (A) & (B) is 14
30. Which of the following is/are more reactive than benzene towards electrophilic
substitution reaction of same kind
CH3 NO2 C2H5 CN
A) B) C) D)

SECTION-II
31. 3.65 gm equimolar mixture of NaOH and Na2CO3 is titrated against 0.1 M HCl using
phenolphthalein as indicator, V1 mL of acid was required to reach end point. In another
experiment, 3.65 gm of the same mixture is titrated against 0.2 M HCl using methyl
orange as indicator, V2 mL of acid was required to reach end point. V1  V2  is x , then
x
what is the value of ?
25
32. Among the triatomic molecules/ions, BeCl2 , N 3 , N 2O, NO 2 ,O3 ,SCl2 ,ICl2 ,I3 and XeF2 ,
the total number of linear molecule(s)/ion(s) where the hybridization of the central atom
does not have contribution from d-orbital(s) is
[Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54]
33. The uncertainity in position and velocity of a particle are 1011 m and 5.27 1024 m / sec
respectively. What is the minimum mass of the particle in kg.
34. The circumference of the second orbit of an atom or ion having single electron is 4nm.
Find the deBroglie wave length of electron in nm revolving in this orbit.
35. How many of the following are correct
i) B < Ga < Al < In < Tl atomic radius order
ii) C > Si > Ge > Pb > Sn IE1 order
iii) C > Pb > Si = Ge = Sn electronegativity order
iv) Li < K < Na < Rb < Cs density order
v) Cl > F > Br > I electron gain erthalpy (magnitude only)
vi) HF > HCl > HBr > HIacidic nature

36. A sample of H atoms containing all the atoms is some excited state is irradiated with the
light of wavelength  and atoms get re – excited to further higher excited state. On
removing the light source, atoms de – excite to the ground state with the emission of
radiations. The emission spectrum thus obtained consists of ten spectral lines. Out of
these ten spectral lines, seven lines have wavelengths smaller and only two line have
wavelengths longer than  . The orbit number for initial excited state is
The number of lone pairs of ‘Xe’ present in equatorial position in  XeF5 


37.
38. Find the total number of possible alkyl chloride in the following reaction-
+ R  Cl 
Anhyd
AlCl 3

39. C2 FClBrl 

H 2 / Ni
 X (Excluding Stereoisomers)
 All isomers 
C4 H 8  alkene  
H 2 / Ni
 Y (Excluding Stereoisomers)
 All isomers 
Find the sum of number of products X and Y .
x
40. Number C-C bonds present in 1 unit cell of diamond is ‘x’. Value of is
2

MATHEMATICS Max Marks : 60
SECTION-I
41. Consider an equation 8x 4  16x 3  16x 2  8x  a  0 then the sum of all the non-real roots of
the equation can be  a  R 
1
A) 1 B) 2 C) D) 3
2
42. Let p, q be integers and let ,  be the roots of the equation x 2  2x  3  0 where    if
n = 0, 1, 2, 3, …. Let a n  pn  qn where n  0,1, 2,.... then the value of a 9 is equal to
A) 3a 8  5a 7  3a 6 B) a 7  6a 6 C) a 7  12a 5  18a 4 D) 2a 8  3a 6
z 1 e i
43. If the imaginary part of the expression  be zero z  C,  R , then
e i z 1
A) z min  1 B) z max  3 C) z min  0 D) z max  2
44. Which of the following options is/are correct ?
A) The least value of 8 z  7  6 z  5 , z  C is 12
z  7  11i z  5  i z  4
B) The least value of   ; z  C is 12
2 2 2
C) The least value of z  3  4i  z  i  z  z  1 ; z  C is 5  2
D) The least value of z  3 2  z  5  2i 2  z  1  i 2 ; z  C is 10
45. Which of the following options is/are correct ?
A) Number of complex numbers ‘z’ satisfying z3  z is 5
B) If the equation z3   3  i  z2  3z   m  i   0 where i = 1 and m  R , has atleast one

real root, value of m can be 1

16
C) If the complex number z  z  2  satisfies the equation z 2  4z  z 2  3
then the value
z
of z 4 is 4
D) All the roots of the equation 11z10  10iz9  10iz  11  0 lie on unit circle  z  C, i  1 
2 2
The equation 
x   x 
46.     a  a  1 has
 x 1   x 1 
A) four real roots of a > 2
B) four real roots if a < -1
C) two real roots if 1  a  2
D) no real root if a < -1
47. Consider the system of equations logax .logaxyz   48, logay .logaxyz  12, logaz .logaxyz  84 where
a > 0, a  1 , then which of the following may be correct ?
A) xyz  a12 B) xyz  a 12 C) x 2  yz D) z  a 2 xy
48. If a, b, c, d are four unequal positive numbers which are in A.P. then
1 1 1 1 1 1 1 1 1 1 4
A)    B)    C) ad < bc D)  
a d b c a d b c b c ad
49. Let a n  be a sequence of real numbers such that a1  2, a n 1  a n2  a n  1 and

1 1 1 1
S    ....  then
a1 a 2 a 3 a 2019
1
A) S < 1 B) S  1 
 2018 2018
1 1
C) S  1  D) S  1 
 2018  2018
 2019 2019

50. Let m, n be real numbers satisfying the relation
 2 2 
 1 2sin  
 7 
  4  
log 2

m 2  n 2 1   2cos 7  
 log 3  
 log n2  log 2
2m  2 n 
Identify which of the following statement(s)
is/are correct ?
A) m + n = 2 B) m  n  4
C) Area of the figure enclosed by |x| + |y| = |m| + |n| is 8 sq. units
D) Area of the figure enclosed by |x| + |y| = |m| + |n| is 16 sq. units
SECTION-II
51. If x 3  ax 2  bx  c  0 has the roots  2  3   4 , 2   3   4 and  2   3   4 where , , 
are the roots of x 3  x 2  1  0 then the value of a + b + c is equal to
8
r  8
 r 
Let a   Tan 2 
a
52. 
 17 
and b   Tan 2   , then
 17  b
is equal to
r 1 r 1
 xy
53. Let ‘S’ be the set of ordered triples (x, y, z) of real numbers for which, log10  z and
log10
 x 2  y2   z  1 . Suppose there are real numbers ‘a’ and ‘b’ such that for all ordered
triples (x, y, z) in S, we have x 3  y3  a . 103z  b.102z then the value of 16a + b is equal to
54. If 1  log5
 x2 1  log ax2 4x a  is true for all x, then the range of a is (p, q], find p + q
5
k   k 
55. For any integer k, let k  cos    i sin   where i  1 . The value of the expression
 7   7 
12
  k 1   k
k 1 is
3
  4k 1   4k 2
k 1

56. If z1 , z 2 , z3  C satisfy the system of equations given by z1  z 2  z3  1, z1  z 2  z3  1 and
z1z 2 z3  1 such that Im  z1   Im  z 2   Im  z 3  ( I m  z  represents, imaginary part of z) then
square of the value of z1  z 22  z33 is ….
57. Let S  z / z z   3  4i  z   3  4i  z  21  0 , If M and m be the maximum and minimum
 zz 
value of   then find 1  1 is
i zz
   

M m
58. If z1 and z 2 be two distinct complex numbers satisfying z12  z 22  z12  z 22  2z 1 z 2 and If
a
 arg z1  arg z2   then least possible value of |a + b| is (a, b  integer)
b
Let  x 3  px 2  2x  5   x 2  qx  41  x 4  x 3  x  7 
19 8 6
59.
= x97  391x96  a 95x95  a 94 x94  ....  a1x  a 0 be an identify where p, q, a 95, ....a 0 are integers,
then the smallest positive value of p.

8 b
60. If   a  c where a, b, c are natural
r 1  2r  1  2r  3 2r  5    2r  3  2r  1 2r  1 3
c
numbers then the value of a  b  is equal to
4

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Sec: OSR.

IIT_N-SC Date: 01-05-21

Name of the Student: ___________________ H.T. NO:

PHYSICS: Kinematics, Laws of Motion, Friction, Work Power Energy, Circular

SR.IIT_N-SC/ N-C Page. No. 2

Strive for Progress, Not perfection.

Total time for the round trip

D) depend on the direction of wind.

SR.IIT_N-SC/ N-C Page. No. 3

Strive for Progress, Not perfection.

A) If F = 0 the blocks can not remain stationary

D) The limiting friction between m2 and M0 is independent of F

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A) If 1>2, the blocks will always remain in contact

B) If 1<2, the blocks will slide down with different accelerations

C) If 1 >2, the blocks will have a common acceleration 1

C) Energy of ball is conserved from position 1 to position 3

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B) v  v0 .e  S / R after it has moved S meter

C) v  v0 .e SR after it has moved S meter

D) Impulse on wedge due to surface is mv0

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C) T1 – T2 = 2mg D) BP will remain taut only if  2g

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The maximum extension of the spring is(in cm)

20. A homogeneous rod of mass 3 kg is pushed along smooth horizontal surface by a

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solution termed as X. 200 mL of the solution X of I 2 required 50 mL hypo solution for

A) Volume strength of remaining H 2O2 solution will be 6.62 V .

B) Molarity of I 2 in solution X is 0.025 M.

C) Molarity of hypo solution taken is 0.2 M.

D) Moles of tetrathionate ions formed will be 0.01.

22. For the reaction,

MnO2  s   4 HCl  MnCl2  2 H 2O  Cl2 ( g )

Select the correct statement(s) amongst the following :

A) MnO2 is the limiting reagent.

B) Chlorine gas produced contains 15  1023 molecules.

C) Moles of excess reactant left is 0.5 moles.

D) If % yield of reaction is 50 %, then moles of MnCl2 obtained will be 2.5

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25. Which of the following is/are correct about sheet silicates

A) PH4  H2O  OF2  SF2 B) PF3  PCl3  PBr3  PI3

C) BF3  CH4  NH3  NF3 D) BF3  BCl3  BBr3  BI3

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Which product(s) is/are formed during the above reaction?

Which of the following is/are correct

A) (A) & (B) both have same number of sp 2 carbons

B) (B) is glyoxal and (A) methyl glyoxal

C) (A) has both sp 2 & sp3 carbons

D) Difference in molecular weights of (A) & (B) is 14

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