Solutions Chemistry: Alo Mgo Nao Ko

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Sri Chaitanya IIT Academy 16-09-17_Jr.Super60-1_JEE-ADV_2011_P2_WAT-18_Key &Sol’s
SOLUTIONS
CHEMISTRY
1. D.
Due to the larger size of hydrated Li  ion conductivity decreases.
2. A
As metallic character of element attached to oxygen atom increases, the difference
between the electronegativity values of element and oxygen increases and thus basic
character of oxides increases and vice versa, Hence, the increasing correct order of
basic nature is Al2O3  MgO  Na2O  K2O
3. C
0
350 C
2 Na  O2   Na2O2 ; 2 Na2O2  2CO2  2 Na2 CO3  O2
4. D
BeO  C  Cl2  BeCl2  CO
(y)
BeCl2  2 H 2O  Be  OH 2  2 HCl
(z)
5. C

BaC2  N 2   Ba  CN  2

CaC2  N 2   CaCN 2
6. A)
Al2 O3  6HCl  2AlCl3  3H 2 O

AlCl3  6NaOH  Na 3 Al OH3   Na 3AlO3  3H 2 O
B)
Al2 O3  6HCl  2AlCl3  3H 2 O

AlCl3  3NaOH  Al OH3   Al2 O3  3H 2O
C)
Al2 O3  6HCl  2AlCl3  3H 2 O(Not AlO2  )
AlCl3  3NaOH  Al OH3
D)
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Conc 
Al2 O3  NaOH  AlO 2  
NaOH
 Na 3 Al OH6    Na 3 AlO3  3H 2 O
7. C
H 3 BO3  3C2 H 5OH   C2 H 5  BO3  3H 2O
Methyl borate
(green flame)
8. C
2 
 B4O5  OH  4   5 H 2 O  2 B  OH 3  2  B  OH  4 

or  B4O7 2  7 H 2O  2 B  OH 3  2  B  OH 4 
9. ABD
The solubility of the alkali metal carbonates increases down the group from Li to Cs.
This is because of the fact that down the group with increasing size of cation the
lattice energy as well as hydration energy also decrease but the change in lattice
energy is more as compare to that of hydration energy. lithium hydrogen carbonate is
not obtained in the solid form while all other elements form solid hydrogen
carbonates.
b) K2CO3 cannot be prepared by solvary process because intermediate formed, KHCO3 is
appreciable soluble in water.
c) Li2CO3 and MgCO3 both are not thermally stable.
d) Fact ref. NCERT
10. ABD
K 2 SO4  CaSO4
Water soluble Insoluble

11. AC
Conceptual
12. ABCD
A) Boron do not contain vacant d-orbitals will Al contain vacant d-orbitals.
fast
 2BH3
B2 H 6 
B)
slow
BH3  H 2 O   products
C) Due to steric hindrance in 2,6-dimethyl pyridine.

D) B OH3  2HF2  BF4  2H 2O  OH  or H3BO3  2KHF2  KBF4  2H 2O  2KOH
 
13. 2
Out of s-black elements Be and Mg do not impart any colour to flame.
14. 7
8 moles of a mixture of Li 2 CO3 and KHCO3 contain 3:1 ratio means it contain 6 moles
of Li 2CO3 and 2 moles KHCO3 .
On heating, Li2CO3  Li2O  CO2
2KHCO3  K 2 CO3  H 2 O  CO 2
6 moles of CO2 will be evolved on heating 6 moles of Li2CO3 and 1 mol. of CO2 is
evolved from 2 moles of KHCO3
15. 3
2Cr OH 3  3 Na2O2  2 Na2CrO4  2 NaOH  2 H 2O
16. 7
OH
B O
O OH
O B
HO-B
O O
B
OH
17. 6
B2 H 6  6 H 2O  2H 3 BO3  6 H 2
18. 8
O O
HO OH
B B
HO OH
O O
Peroxoborate
19.  a  r , s  ;  b  r  ;  c  pqrs  ;  d  q 

a)solvay process is used for the manufacture of NaHCO3 and Na2CO3 ;the raw material
is NaCl

b) 2NaHCO3   Na2 CO3  CO2  H 2 O
c) Na2O  2H 2O  2 NaOH ;NaOH being basic turns red litmus blue.

Na2O2  2 H 2O  2 NaOH  H 2O2 ;NaOH being basic turns red litmus blue but H 2O2 being
agent bleaches coloured litmus.

NaHCO3  H 2O  NaOH  H 2CO3 solution is alkaline and turns red litmus blue.
d) Na2O2  CO2  Na2CO3 ; 2 Na2O2  2CO  2 Na2CO3  O2 ,Hence, it absorbs CO and CO2
and liberates oxygen.
20.  a  pq  ;  b  p, s  ;  c  p, r  ;  d  p 
Reactions are 
Re d
B2 H 6 
heat
 2 B  3H 2
B2 H 6  6 H 2O  2 H 3 BO3  aq   6 H 2
AlCl3
B2 H 6  HCl   B2 H 5Cl  H 2
0
200 C
B2 H 6  NH 3   B3 N 3 H 6
(Borazole)
(Inorganic benzene borazine)
PHYSICS
21. Compare the standard moment of inertias of the bodies
22. IA 
8 r t  r
2 2
 t  16r 2 / e
, I B   8 16r 2  , I B  64I A
2  4 2
23. The different forces on the block are shown in figure.

y
f
F x
x
N
mg
For equilibrium, f  mg
And normal reaction ,N=F
Torque due to F  0 (F passes through centre)
As the body is in equilibrium and hence, torque due to friction about centre of mass is
equal to torque due to normal reaction about centre of mass.
24. From figure shown
a
T2
T1
a2
a1
40N
50N
50  T1  5  2 
T2  40  4  
T1  2   T2 1  4
From (1),(2) and (3),

2  50  10    40  4   4
 100  20  40  4  4
 28  60
60
   2.1m / s 2
28
25. For equilibrium of rod considering limiting friction we use
f1  N 2
 N1  N 2
 w  N1  f 2  0
N1   N2  w
N1   2 N1  W

f2
B
N2
5m
N1 4m
w

A O
f1
Balancing all torque about point A, we use

 3
 w    f 2  3  N 2  4   0
 2
3W
`   3 f2  4N2  0
2
3
 3 N 2  4 N 2   w
2
3
  N1  3 2  4   N1 1   2 
2
2  3 2  4    3  3 2
6  2  8  3  3 2
3 2  8  3  0
 3 2  9    3  0
3    3  1   3   0
1
  As   3
3
26. As
M
2 1
1
I I full square
4
1
 M full l 2 full /12
4
2
1
I   4m 
2l  
4 12

Ml 2
I
6
27. Using parallel axis theorem
I CC1  I B  Mb 2
I AA1  I CC1  Ma 2
A B
C1
A1 B1
a b
 Ml 2 
28. I   24M  R 2  24  
 3 
 24Ml 2  8Ml 2
I  32Ml 2
 
29. Applying net torque=  ri  Fi
30. B,C
From figure we have
1 3
IY  mR 2 & I X  I Z  mR 2
2 4
31. Case 1:
FR  I 
40  0.25  4
5
  rad / s 2
2
1  2
l
 2
r
5 5
 2 
2 0.25

= 10 rad/s
Case 2:
40
Mass of the block is m   4kg
10
For conservation of energy ,
[Loss in GPE of 4 kg mss] = [Gain in KE of 4kg mass] + {Gain in RKE of Cylinder]
1 2 1 2
mgh  mv  l
2 2
As v  R ,
1 2 1
mgh  m  R   l 2
2 2
2
1 1 1
 410 5   4    2   4  2
2 4 2
40
 2  rad / s
17
32. As the sphere is rotating uniformly the tangential acceleration of any particle on
sphere will be zero and all particles will only have normal acceleration.
33. N 2 L  block
T  50  10  50  2  T  600 N
2
&1   F  0.10  0.25  600
0.25
 0.10 F  8  150
34. Just after the thread is burnt

Spring force=  600  0.01  6N remains same
Torque equation= I  6  0.60  20  0.10  c.w
 12 
 2   0.01   5.6
 12 
5.6  12
 
2 1.12
5.6 12
Applying = N 2 L  6  20  N  2  0.10 
2 1.12
 N  20
35. Torque equation (discus)

 I1  I 2    rT
1
N 2 L  block
mg  T  mr1
36. A rod of length l is pivoted about an end. Find the moment of inertia of the rod about
this axis if the linear mass density of rod varies as   ax 2  b kg / m
As mass of the rod varies with its length, here we cannot use the expression
Ml 2
.which is only used for uniformly distributed mass along the length of rod pivoted
3
at an end. In this case we consider an elemental length dx from the axis at a distance
x.Let its mass be dm ,where
dm   dx
  ax 2  b  dx
During rotation of rod this dm revolves in a circle of radius x, hence its moment of
inertia dl is given as
dl  dmx 2
  ax 2  b  x 2 dx
The moment of inertia of the whole rod is given by integrating the above expression
1
within limits from O to l as I    ax 2  b  x 2 dx
0
l
 ax 5 bx3 
Or  
 5 3  0
al 5 bl 3
Or  
5 3
Ml 2 l
37. i) 1  mg cos530
3 2
Ml 2 l l
ii)  1  mg cos530  mao sin 530
3 2 2
 a0 sin 530  2 g cos 530
3 3
a0  2 g  g
4 2

2
38. I3  I1  I 4  MR 2
3
2 5
I2  MR 2  MR 2  MR 2
3 3
2 5
 I1  I 2  I 3  I 4  3 MR 2  MR 2
3 3
11 11
 MR 2  I1
3 2
39. dm   Rd
dI z  R 2 sin 2  dm  I x   R 2 sin 2  dm
dI y  R 2 cos 2  dm  I y   R 2 cos 2  dm
dI z  R 2 dm  I z   R 2 dm
40. Applying rotational equation and then applying torque equation about the respective
pivots
MATHS
4 4 4
41. Given L   1  2   1  2  1  2  .........
3  4  5 
 2   2   2   2    2   2   2  
 1   1   1   1   .....  1   1   1   ....
 3   4   5   6    3   4   5  
1 2 3 4   5   6   7  
      .....        ......
3 4 5 6   3   4   5  
1 2 1
   
3 4 6
(Remembering terms in two braces are reciprocal of each other)

23  1 33  1 43  1
Also, M  , , ....
23  1 33  1 43  1
x3  1  x  1  x  x  1 
2

 Now 3  
 x  1  x  1  x 2  x  1 
 
 2 1 3  1 4  1 5 1 
M  , , , ....  
 2  1 3 1 4 1 5 1 
 22  2  1   32  3  1   42  4  1 
 2  2  2 
 2  2  1   3  3 1   4  4  1 

1 2 n 2  n  1 2
M  lim  ;
n   n  1 n  3 3
2
 1
 
1 
N   n
 Lt 
 n  1 2 / n2
n 1  2  n  n  2 / n
1  
 n
n   r  12 
 Lt   
n  
r 1 r  r  2 

 
 n r 1 r 1 
 Lt   . 
n 
 r 1 r r  2 
2 3 4 n 1   2 3 n 1 
 Lt     ....       ...  
n  1
 2 3 n  3 4 n2
 2  n  1 
 Lt  2
n 
 n2 
1 3 1
L1  M  N 1  6    8
2 2
1
 n 
  4
42. lim 4  r  1 r  2  r  3    n 

n  
 r0 
 
1
 
  4  n  1 n  2  n  3  n  4   4

lim 
n 
  n
4
   
1
 
lim  n  1 n  2  n  3 n  4  4  n 
n
 
1
 
 1   2  3   4   4
lim n 1   1   1   1     n 

n  
 n   n  n   n  
 
  1   2   3   4  1/ 4 
  1    1   1   1     1 
 n   n   n   n 
lim   
n   1 
 n 
 
 1  x 1  2 x 1  3 x 1  4 x 1/4  1 

lim  
x 0  x 
 

 1  10 x  35 x 2  50 x 3  24 x 4 1/4  1 
lim    10  5  By L.H .Rule 
x 0  x  4 2
 
43. 2  f  x  f  y   f  x   f  y   f  xy  ; y  x
2
2   f  x    2 f  x   f  x 2 
put x  1;
2
 2  f 1  3 f 1
2
  f 1   3 f 1  2  0
  f 1  1  f 1  2   0
1
 f 1  1 or f 1  2, Re placing y by
x
1 1
 2  f  x . f    f  x   f    f 1
x  x
1 1
 2  f  x  . f    f  x   f    f 1
x  x
If f 1  2
1 1
 f  x   f    f  x . f  
x x
 f  x   1  x 2 but f  2   5
n
 1  2
 n  2 and f  x   1  x 2
If f 1  1, Then 2  f  x 1  f  x   1  f  x 
 f  x   1x  R
But f  2   5
 f 1  1
f  x   1  x 2 which is a continuous function
lim f  5  1  52  26
x5
1
44. lim  a x  e x  x  a, a  0
x 

x 1/ x
a  lim  a x  e 
x 
ln  a x  e x 
 ln a  lim
x  x
This gives as  /  format.
 a x ln a  e x 
Hence L.H rule, we get lim Lna   x x 
x 
 a e 
 a x ln a  e x 
lim Lna   x x 
x 
 a e 
 a   e,  
n n n
r r
45.  t   1  3r
r 1
r
r 1
2
r 4

r 1  r  1 2  r 2 
2
 
1  r  r  1   r  r  1
n 2 2

r 1 2  r  r  1 r  r  1
2 2
1 n  1 1  1 1 
    
2 r 1  r 2  r  1 r 2  r  1  2 
1 
 n 2
 n  1



1  n 2  n  1  1  1   n2  n  n
1
  2   2
2  n  n  1  2  n  n  1
 ; lim
n 

r 1
tr 
2
3
46. Here tan 1 2 x  1


 tan 1  2 x    2x  3
3
3
For 2 x  3,  tan 1 2 x   1
 
2
3 
  tan 1 2x    as n  
  
1
 lim 2
0
n 
3 1 
 tan  2 x   5
 
 f  x   0 for 2 x  3
  1  
47. lim  f  x   ln  1  f  x    ln  f  x   
x 0
  e  

 
lim  f  x   ln e f  x   1  ln e f  x   ln  f  x   
x 0  
  e f  x  1 
 
lim ln e f  x   1  ln f  x    lim ln 
x 0   x 0   f  x   
  
 0 if f  x   0 as x  0
As f  x  is defined x  R
f  0  0

sec2
    2 bx
48. lim  sin 2  
x 0
  2  ax  

sec 2
    2  bx
Let k  lim  sin 2  
x 0
  2  ax  
Taking ln both sides, ln k

    
 sec 2 ln  sin 2  
2  bx   2  ax  
  2   
 ln  sin  2  ax   
 
 ln k  lim  
x 0 
2   
 cos  1  bx  
 
a2
By L.H rule, we get ln k  
b2
a2

b2
k e
49. a,d
f 1  0   lim  1  h  1   1  h  lim h  1  1
h 0 h 0
f 1  0   lim  1  h  1   1  h  lim h  0  0
h 0 h 0
50. b.c
Since the greatest integer function is discontinuous (sensitive) at integral values of x,
for a given limit to exist both left0and right-hand must be equal.
L.H .L  lim  2  x  a  x  1  b 1  x  
x 1
 2  1  a  1  b 1  1  a  b

R.H .L  lim  2  x  a  x  1  b 1  x  
x 1
 2  1  a  0   b  2   1  2b
On comparing, we have –a=b

51. a,b,c,d
tan 2  x
We have lim f  x   lim
x  0 h  0
x 2 2
  x 
tan 2 x
 lim 1 ……1
x0 x2
Also lim f  x   lim x cot x  cot1 ……2

k 0 x0
 x  0,  x   1   x  x  1  x  1
2

Also, cot 1 lim f  x 
x 0
  cot 1
 cot1  1
52. a,b,c
x3
cos 2 x  cos x  e x cos x  e x 
53. Given that lim 2
x 0 xn
x3
 cos x  1  cos x  e x  
 lim 2
x 0 xn
 x5 x4 x6   x2 x4   x2 x3  x3
 1     .....  1  1    ...... 
  1  x    .... 
 2! 4! 6!   2! 4!   2! 3!  2
 lim n
x 0 x
= n=4
54. Conceptual
n
  2 x 

 n   k  sin x    1
lim
x
55. lim  k 1
3
  lim  sin x 
x0 
 n  3 x  0 
 
L=1/3

2n tan
56. f  n,    2n
tan 

 lim f  n,  
n  tan 

 3 f  x  1 
57. lim  f  x   3
x   f 2  x  

 3lim f  x   1 

or lim f  x   x 3
 x 

 x


2
lim f  x  
 
 3y 1 
or  y  2   3
 y 
or y 2  3 y 2  3 y  1  0
3
or  y  1  0
or y  1
58. m=0,n=2
tan x tan x
59. p)  1 and  1 for x  0
x x
tan x
  1  h; h  0
x
tan x
 200  200  200h; h  0
x
 tan 
  200  200
 x 
sin x sin x
Also  1 and  1 for x  0
x x
sin x
  1  h; h  0 
x
 sin x 
 200    200  200 h; h  0
 x 
 sin x 
  200  199
 x 
 tan x   sin x  
lim   200    200   399
x 0
 x   x  
tan x
q) 100  100 1  h   100  100h; h  0
x
 tan x 
100   100 h  0 as h  0
 x 

sin x 
Also 100   100 1  h   100  100h
 x 
99  1  100h   1 100h  1 as h  0

 tan x   sin x 
lim 100   100   0 1  1
x 0
 x   x 
sin x
r)  1  h; h  0 as x  0 
x
 sin x  x
   1  h   0 and  1 for x  0
 x  tan 1 x
x
  1  h; h  0
tan 1 x
 x 
  1   1
 tan x 
  sin x   x 
lim 100    200  1    0  200  200
x 0
  x   tan x  
sin  x sin 1 x
s)As x  0,  1and  1 as x  0
x x
sin 1 x
  1  h; h  0 
x
 sin 1 x  
   h  0 as h  0
 x 
tan 1 x tan 1 x
Also  1 and  1 as x  0
x x
tan 1 x
 200  200 1  h  ; h  0 
x
 tan 1 x 
  200    200  200h  199
 x 
60.  p   d ;  q   c;  r   a ;  s   b
ao x m  a1 x m1  ....ak x m k
  x 
b0 x n  ....  bl xl e
 a  a x  ......ak a k   m n
  x   0 1 l  .x
 bo  b1 x  ......bl x 
p) m  n

 lim   x  
x 0
a0 m n
 0  0  m  n
b0
 p   d 
ao
q) m  n  lim   x  
x 0 bo
q  c
r) m  n
a0  1  a
 lim   x      if 0  0, n  m  even
x 0 bo   0  n m 
 b0
r   a
 a0 
s)By the similar logic lim   x   ,   0  and n-m is even
x 0
 b0 
s  b

Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Jr. Super60-I Date:23-09-17
Time: 07:30 AM to 10:30 AM Max.Marks:180
Name of the Student: ___________________ I.D. NO:
2014_PAPER-I
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
23-09-17_Jr.Super60-I_Jee Adv_WAT-19_Weekend Syllabus
MATHS: SYLLABUS COVERED FROM 18-09-17 TO 21-09-17
PHYSICS: SYLLABUS COVERD FROM 18-09-17 TO 22-09-2017
CHEMISTRY: GROUP 13: Preparation, properties and uses and aluminium, alumina,
aluminium chloride and alums, Group 14, Water, heavy water, H2O2
Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

JEE-ADVANCE-2014-P1-Model
Time: 07:30 AM to 10:30 AM IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30
Total 20 60
CHEMISTRY:
Total 20 60
MATHEMATICS:
Total 20 60
Sec: Jr. Super60-I space for rough work 2


PHYSICS MaxMarks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
1. A wheel is rolling without slipping on a horizontal plane. At a certain instant, it has
velocity ‘v’ and acceleration ‘a’ of centre of mass as shown in the figure. At that
instant, acceleration of
C
a
B
v
A
‘A’ is point of wheel.
A) A is vertically upwards
B) B may be vertically downwards
C) C cannot be horizontal
D) some point on the rim may be horizontal in forward direction.
2. A sphere is thrown along a rough surface as shown. Mass of the sphere is M and
radius is R. If t is total time taken to start pure rolling after thrown, then:

5v0
A) speed of the sphere when it starts pure rolling is
7
t
B) work done by friction is greater in first half i.e. 0 to compare to later half
2
t
i.e., to t
2
C) work done by friction is zero after time t
1
D) the net work done on the sphere is Mv02
4
3. An uniform solid cylinder is placed on a horizontal board. The coefficient of friction
between them is 0.3. The board is imparted a constant acceleration of a 6m / s 2 in a
horizontal direction at right angles of the cylindrical axis. Then (take g 10m / s 2 )

A) The acceleration of the cylinder axis in the absence of slipping

will be 1.5 m / s 2 .
B) The acceleration of the cylinder axis in the absence of slipping will be 2 m / s 2
C) The limiting value of ‘ a ’ for which there will be no slipping is 12 m / s 2
D) The limiting value of ‘ a ’ for which there will be no slipping is 9 m / s 2
4. A disc of mass m and radius R moves in the x-y plane as shown in the fig. The
angular momentum of the disc at the instant shown is:
y
3R
x
O B
4R
5 7
A) mR 2 about O B) mR 2 about O
2 2
1
C) mR 2 about A D) 4mR 2 about A
2

5. A thin uniform rod of mass 5 kg and length 1 m is held in horizontal position with the
help of strings attached to ends of rod. Other ends of strings are held by some external
agent. Now end A is pulled down with speed VA 3 t and end B is pulled down with
speed VB t where t is time in s. Choose the correct choice (s) at time t 0 .
A) Angular acceleration of rod is 2 rad / s 2

185
B) Tension in left string is N
6
C) Acceleration of rod is 1 m / s 2
170
D) Tension in right string is N
3
6. A small mass m is attached to a massless string whose other end is fixed at P as shown
in the figure. The mass is undergoing circular motion in the x-y plane with centre at O


and constant angular speed . If the angular momentum of the system calculated about
O and P are denoted by LO and LP respectively, then
z
m
O
A) LO and LP do not vary with time

B) LO varies with time while LP remains constant
C) LO remains constant while L P varies with time
D) LO and LP both vary with time.
7. A sphere of mass m and radius ‘r’ is released from rest from the top of a wedge of
mass ‘2m’ initially at rest on a smooth horizontal surface as shown. There is sufficient
friction between the sphere and the wedge so that the sphere rolls on the wedge
without slipping. The sphere leaves the wedge horizontally at A after descending
through a vertical displacement h. Let V1 ,V2 and be the magnitudes of the velocity


of the centre of sphere, velocity of wedge and the angular velocity of the sphere at the
instant the sphere leaves the wedge. Choose the correct statements.
A) V1 V2 r
B) Total mechanical energy of sphere and wedge system is conserved during the
process
C) The ratio of total kinetic energy of the sphere and to the wedge at the instant the
sphere leaves the wedge is 19:5
5 gh
D) V1
6
8. A uniform rod AB of length ‘L’ mass M is suspended by two massless identical
threads. Initially the rod AB is in equilibrium in the horizontal position and the
system is in vertical plane as shown in fig. Immediately after the thread (1) breaks,
(take g is acceleration due to gravity)

Mg sin
A) Tension in thread (2) is
1 3sin 2
6 g sin 2
B) Angular acceleration of the rod about it’s centre of mass is
L 1 3sin 2
C) The end A of the rod has acceleration component in vertically upward direction
D) Centre of mass of the rod has horizontal acceleration component towards leftward
9. A solid sphere is given an angular velocity about a horizontal axis and kept on a
rough fixed incline plane. Then choose the correct statement.


A) If tan , then the sphere will be in linear equilibrium for some time and after that
pure rolling down the plane will start.

B) If tan , then the sphere will move up the plane and frictional force acting all the
time will be 2mg sin .

tan
C) If , then there will never be pure rolling (consider inclined plane to be long
2
enough.)
D) If incline plane is not fixed and it is on smooth horizontal surface then linear
momentum of the system (wedge and sphere) can be conserved in horizontal
direction.
10. Friction between the wedge shown and the horizontal floor is sufficient to prevent the
wedge from sliding. The mass of the wedge is M and its angle of inclination is . A
small block of mass m is just placed near the top of the wedge and released. Friction
coefficient between the wedge and the block is .


m
A) If tan , the wedge will not topple for any value of m.
M
B) If tan , the wedge will topple for m .
3sin sin cos
C) The wedge will topple for any value of m irrespective of .

M
D) If tan , the wedge will not topple for m .
3sin sin cos
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).
11. A rectangular rigid fixed block has a long horizontal edge. A solid homogeneous
cylinder of radius R is placed horizontally at rest with its length parallel to the edge
such that the axis of the cylinder and the horizontal edge are in same vertical plane
shown in the figure. There is sufficient friction present at the edge, so that a very small


displacement causes the cylinder to roll off the edge without slipping. Then the ratio
of the translational to rotational kinetic energies of the cylinder when its center of
mass is in horizontal line with the edge is......
12. An ideal string is wrapped several times on a solid cylinder of mass 4 kg and radius 1
m. The pulleys are ideal and the surface between block and ground is smooth.
Cylinder rolls without slipping on the block. If the torque acting on the cylinder is
10x
N-m, then find the value of x.
9


13. A uniform rod of length 2 and mass m is suspended from one end by an inextensible
vertical string and other end lies on smooth ground. The angle made by rod with
1
vertical is sin 1/ 3 . If N 1 and N 2 represents the contact force from ground on rod
just before and just after cutting the string then find the ratio of N 1 / N 2 .
14. A solid cone of mass (m = 1 kg) is placed on a plank of mass M = 1 kg which is

placed on a smooth horizontal plane. The coefficient of friction between cone and the
plank is 1/4. If a horizontal force F is applied on the plank, then find the maximum
value of F for which the cone is in equilibrium with respect to plank.
(Take g = 10 m/s2 and H/r = 20)
H
rm
M F
15. The solid semi-cylinder of mass m and radius R is rolled slowly through an angle by
the horizontal force P. If the coefficient of static friction is s, the angle at which


the cylinder begins to slip on the horizontal surface as P gradually increased is
1 3
sin s
.Find ‘n’.
n 3 s
16. A solid cylinder of mass m = 4 kg and radius R = 10 cm has two ropes wrapped
around it, one near each end. The cylinder is held horizontally by fixing the two free
ends of the cords to the hooks on the ceiling and both the cords are exactly vertical.
The cylinder is released to fall under gravity. The linear acceleration of the cylinder is
n
g then n = ?.
n 1


17. A disc of radius 0.1 m rolls without sliding on a horizontal surface with a velocity
of 6 m/s. It then ascends a smooth continuous track as shown in figure. The height up
x
to which it will ascend is m . Value of x is? (g =10m/s2)
5
6m/s
18. A constant power is supplied to a rotating disc. Angular velocity ( ) of disc varies
with number of rotations (n) made by the disc as n1/x. Value of x is


19. A semicircular ring of mass m and radius r is released from rest in the position shown
with its lower edge resting on a horizontal surface. The minimum coefficient of static
x
friction s which is necessary to prevent any initial slipping of the ring is . Value of
10
x is
20. A binary star consists of two starts A (mass 2.2Ms) and B (mass 11Ms), where Ms is
the mass of the sun. They are separated by distance r and are rotating about their
centre of mass, which is stationary. What is the ratio of the total angular momentum of
the binary star to the angular momentum of star B about the centre of mass?


CHEMISTRY Max Marks: 60
SECTION-I
This section contains 10 multiple choice equations. Each question has four choices (A) (B) (C) and (D) out of which
ONE or MORE are correct.
21. The correct propertie (s) about Boron and Aluminium is/are:
A) Maximum Covalency of Boron is 4 and that of aluminium is 6
B) Aluminium dissolves in dilute alkali and liberate H2 but Boron does not
C) Oxide of Boron is acidic where as that of aluminium is amphoteric
D) Halides of Boron exist as monomers where as the halides other boron family
members exist as dimers.
22. Identify the correct statement(s) regarding hydrogen gas
A) Unlike H2, D2 do not show spin isomerism.
B) Orthohydrogen differs from parahydrogen w.r.t their b.p., sp. Heat and thermal
conductivity
C) As the temperature is increased from absolute zero some of the para form gradually
changes to ortho form.
D) Parahydrogen has lower internal energy than orthohydrogen.


23. The correct statement(s) is/are
A) I.E1 of Pb > I.E1 of Sn
B) CO2 , SiO2 & GeO2 are acidic, SnO2 & PbO2 are amphoteric
C) SiF62 is known but SiCl62 is not known

D) C Si Ge Sn (Catenation)
24. The correct statement(s) is/are:
A) The only solid bicarbonates known are those of the group-1 metals and of NH 4
B) Carbon monoxide is quantitatively estimated by I2O5
C) CH 4 SiH 4 GeH 4 PbH 4 (Thermal stability)
D) Graphite > diamond > fullerenes (Thermal stability)
25. Which of the following methods can be used for the preparation of anhydrous
aluminium chloride?
A) Heating AlCl3 .6 H 2O
B) Heating a mixture of alumina and coke in a current of dry chlorine gas
C) Passing dry HCl gas over heated aluminium powder
D) Passing dry chlorine gas over heated aluminium


26. Select the correct statement about silicates?
A) Cyclic silicate having three silicon atoms contains six Si O Si linkages
B) On an average over all 2½ oxygen atoms per tetrahedron unit are shared in double
chain silicate
2n
C) Si2O5 n
is the repeating unit or basic unit of double chain silicate
D) SiO44 units polymerise to form silicate because Si atom has less tendency to form
-bond with oxygen
27. The correct statement(s) is/are
A) Does not neutralise dilute HNO3 : SiO2 , PbO2 , CO
B) Reacts with HF : SiO2 , SnO
C) Solid at room temperature : SiO2 , LiHCO3
D) May act as reducing agent : CO, SnO


28. The correct statements among the following are
A) H 2 is more rapidly adsorbed on solid surface than D2 .
B) H-H bond dissociation energy is greater than D-D bond dissociation energy.
C) Deuterated compound can be easily prepared by exchange reaction of deuterium
with hydrogen using heavy water rather than D2 .
D) The bond length is shortest in T2 among the isotopes of hydrogen.

H 2 F2 H 2O
29. SiO2 NaOH A B C D
Hence
A) A Na2 SiO3 B) B SiF4
C) C H 2 SiO3 ; D H 2 SiF6 D) C F2 ; D H 2O2
30. The correct statement(s) is/are about carbides:

A) Be2C and Al4C3 are methanides
B) B4C and SiC are covalent
C) Interstitial carbides retain many of the properties of metals
D) Interstitial carbides are less denser and harder than pure metals

SECTION-II
inclusive).
P4O10 2000 C
31. Malonic acid Foul smell A B +Carbon
1500 C
The total number of sigma and Pi bonds present in the compound A are: ........
12
32. In cyclic silicate ion Si6O18 the number of oxygen atoms shared are: .........
33. The number of oxygen atoms not acting as bridges (Si-O-Si) in the mineral kinoite
Ca2Cu2 Si3O10 .2 H 2 O .
34. How many of the following species have sp 2 hybrid atoms?
Diamond, Graphite, C6O , SiH 3 3 N ; AlF3 ; AlCl3 monomer ; Al2 CH 3 6 ; SiC ,
H3BO3 , layered BN, Borazine.
35. How many of the following compounds are amphoteric?
CO, Al2O3 ; SiO2 : GeO, SnO, SnO2 , PbO, PbO2 , CO2


36. How many of the following reactions produce a paramagnetic gas?
AlH 3 H 2O
Al2O3 C N 2
AlN H 2O
Conc. H 2 SO4
HCOOH
H 2O
Conc. H 2 SO4
CH 2 COOH 2
H 2O
CO I 2O5
Fe2O3 C
37. In how many of the following reactions hydrogen gas is produced as one of the
product.
(i) Electrolysis of acidulated water
(ii) Passing steam over red hot coke.
(iii) Reaction of aluminium with sodium hydroxide
(iv) Reaction of Zinc with dil HCl
(v) Pyrolysis of hydrocarbons
(vi) Reaction of sodium amalgam with water.
(vii) By dissolving hydrolith in water.
(viii) By heating a mixture of steam and hydro carbons
(ix) Electrolysis of brine.

38. How many of them are 3-D silicates?
Feldspars, Ultra marines, Zeolites, Pyroxenes, Amphiboles, Beryl, Zircon, Asbestos
39. X = Oxidation, state of carbon in CO
Y = Oxidation state of carbon in COCl2
They y x is:
40. How many of the following reactions lead to the formation of CO as one of the
products?
COOH 2 ; HCOOH ;
Conc. H 2 SO4 Conc. H 2 SO4
dilute
Al2O3 C Cl2 K 4 Fe CN 6 ;
H 2 SO4
Ni CO 4 B2O3 C


MATHS Max Marks: 60
SECTION-I
This section contains 10 multiple choice equations. Each question has four choices (A) (B) (C) and (D) out of which
ONE or MORE are correct.
1 1
x x
e e
41. Let f x g x 1 1
where g x is a continuous function, then lim f x exits, if
x x x 0
e e
A) g x is any polynomial B) g x x2
C) g x sin x D) g x 2 3x 4 x3
42. Let f : R R be a function given by
5x if x Q
f x 2
where Q is set of rational numbers then
x 6 if x R Q
A) f x is continuous for x R
B) f x is continuous at finite number of values of x
C) f x is continuous at x 2
D) f x is continuous at x 0


43. Let f x be a non constant polynomial function satisfying the relation
f x .f y f x f y f xy 2 for all real x and y and f 0 1, suppose f 4 65 .
Then, which of the following statement(s) is/are true

A) f | x is a polynomial of degree 2
B) Roots of f | x 2 x 1 are real
C) xf | x 3 f x 1
D) f | 1 3
44. Consider the function f : R R defined by f x 2 sin x where is G.I.F, then

which of the following is/are true
A) f x is continuous at x
2
3
B) f x is not differentiable at x
2
C) f x is continuous at x
D) f x is not differentiable at x
2


3
45. Let f : 0, R be defined by f x max sin x, cos x, then which of the following
2 4
is not true.
A) f x is continuous for all real x 0, 2
B) f x is not differentiable at x
4
C) Number of points where f x is not differentiable is 2
D) Number of points where f x is not continuous is 3
sin x x
2 x 5
46. If f x 5 b 1 x 5 is continuous at x 5 , a, b R , then ( denotes
x 2 11x 24 x 5
ab 2
x 3
G.I.F)
773 523 a 125
A) a b B) a b C) a b D)
540 540 b 648


1
x x x if x 0
47. Let f x x (where x denotes the greatest integer function).
0 if x 0
Then the correct statement(s) is/are

A) limit of f x exists for x 1
B) f x has discontinuity at x 1
C) f x has discontinuity at x 2
D) f x is discontinuous at all positive integers
x n sin 1 x 0 n 2
48. The set of points of differentiability of the function f x x
0 x 0
contains (Where R is set of real numbers)
A) ,0 B) R 0 C) 0, D) R
49. Suppose that f : R R is continuous and satisfying the equation f x . f f x 1 , for
all real x . Let f 1000 999 , then which of the following is/are true
1 1
A) f 500 B) f 199
500 199
1 1
C) f x x R 0 D) f 1999
x 1999

1 2x
50. Let f : R , be a function defined by f x sin then which of the
2 2 1 x2
following is/are true

A) f x is not differentiable at x 1 and x 1
B) f x is continuous for all real x
C) f x 2 tan 1 x x R
D) f x is differentiable x R
SECTION-II
inclusive).
x
51. The number of points where f x in x 0, 30 is discontinuous is ( is G.I.F)
3
1 1
2sin x 2tan x
if x 0
52. Let f be a function defined on 1,1 as f x 2 tan x 2sin x then the value
K if x 0
of K such that f x is continuous at x 0 is


ab
2x2 3x x2
53. If f x sin cos x 0 is continuous at x 0 where a, b R {0} and

a b
e3 x 0
K is minimum value of ‘a’ then 4K is equal to
54. The function f x is discontinuous only at x 0 such that f 2 x 1 x R . The total
number of such functions is

55. Number of points where the function f x max tan x , cos x is non differentiable in
the interval , is
x 2 x 0
2
56. If f x x 2 0 x 1 then the number of points of discontinuity of f x is
x x 1
x 3
57. f x a sin x be c x (a, b, c R). If f x is differentiable at x 0 , then the value
of a b is equal to
n
x 1
58. Let g x ;0 x 2 where m 0, n 0 are integer. Let P be the left hand
loge cos m x 1
derivative of x 1 at x 1 and lim g x P , then m n

x 1


59. Let f : R R be a continuous function satisfying f 0 1 and f 2 x f x x then the
value of f 3 is
1 cos 3x cos 9 x cos 27 x....cos 3n x

if x 0
x x x x
60. f x 1 cos cos cos .....cos n If f x is continuous at x 0 ,
3 9 27 3
310 if x 0
then the value of n is n N

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_Jee-Adv_2014-P1_WAT-19_Key Sol’s

Sec: Jr. SUPER60-I JEE ADVANCED DATE : 23-09-17
TIME : 07:30 AM to 10:30 AM WAT-19 MAX MARKS : 180
KEY SHEET
2014-P1
PHYSICS
1 ABCD 2 ABC 3 BD 4 AC 5 AB
6 C 7 ABCD 8 ABD 9 AD 10 AB
11 6 12 8 13 1 14 4 15 4
16 2 17 9 18 3 19 4 20 6
CHEMISTRY
21 AC 22 BCD 23 ABCD 24 ABCD 25 BCD
26 BCD 27 ABD 28 AC 29 ABC 30 ABC
31 8 32 6 33 8 34 7 35 5
36 0 37 9 38 3 39 2 40 5
MATHS
41 BC 42 BC 43 ABCD 44 ABD 45 BD
46 ACD 47 ABCD 48 ABCD 49 AB 50 AB
51 9 52 1 53 1 54 6 55 4
56 1 57 0 58 4 59 4 60 4
Sec: Jr. Super60-I Page 1

SOLUTIONS
PHYSICS
1. At A :
2
V
R
a
R A
for a rolling wheel, a = R

(A) is correct.
At B :
V B
a
R
R
V2
If a then aB may be vertically downwards
R
(B) is correct.
At C :
C R
a
V
R
(C) is correct.
Consider this
V
R
a
(D) is correct.
2
2. mgR mR 2
5
5 g
2 R
t; v v0 gt
For pure rolling, V R


V0 gt R t
2 V0
t
7 g
2 5
V V0 V0 V0
7 7
3. mac Ffr
I rF fr rmac
rmac
a ac r r
I
mr 2 ac
or, a ac 2ac
mr 2
2
a 6
or, 3ac a, ac 2m / s 2
3 3
ma
So, f FR so maximum value of this force is equal mg
3
malim
Hence mg or, alim 3 g 3 0.3 10 9m / s 2
3
MR 2
4. (a) m (R ) (3R)
2
5
mR 2
2
(c) Conceptual
5.

6. L m r rO v
LO m r rO v mre r mre t m r2 z
L m r rP v m rer hz mret mh re r m r2 z
7. V1 2V2 i rw V1 V2 and by conservation of energy
1 1 12 2 2
mgh mV12 2mV22 mr w
2 2 25
5 gh
V1
6
Non-conducing of mass M and radius R
8. T cos macm x
Mg T sin macm y
T sin L I cm
2
And apply thread constrained along length of the thread acceleration is zero.
mg sin
1 3sin 2
6 g sin 2
L 1 3sin 2
9. Due to torque of friction about CM, eventually, decreases to zero, initially there is
no translation. Friction is sufficient for pure rolling therefore after sometime pure
rolling begin. There is no external force in x direction therefore momentum is
conserved along x direction.
10.
m
=mgcos
M
Mg


b
N sin h Mg mg cos h cos
3
b
mg cos .sin h Mg mgh cos 2
3
3m sin sin cos M
M
m
3sin sin cos
2
4
11. from C.O.M.E, g (1 cos )
R 3
m 2
From dynamics of circular motion mg cos
R
1 4
On solving above eqs. cos
7
mgR
KR
7
When the cylinder loses its constant i.e., the frictional force vanishes, also torque due
to gravitational force is zero. Hence its angular velocity is constant and rotational
kinetic energy becomes constant, while its translational kinetic energy increases.
Applying conservation of energy at position (1) and position (3)
Decrease in gravitational P.E. = Gain in rotational K.E. + translational K.E.
mgR 6
KT mgR mgR
7 7
From (3) and (4), we have
6
mgR K
KT 7 or T 6
KR mgR KR
7
1 2 1 2
mgR 0 mgR cos I mv
2 2
v
But
R
1
And I mR 2
2
1 1 1 2
Therefore, mgR mgR cos mR 2 v2 / R2 mv
2 2 2


2
v 4
Or g 1 cos ............... (1)
R 3
When the cylinder leaves the constant, normal reaction N=0 and c . Hence
mv 2
mg cos c
R
v2
Or g cos c ............... (2)
R
From eqns. (1) and (2),
4
g 1 cos c g cos c
3
4
Or cos c
7
1 4
Or c cos
7
All the time it leaves the contact,

cos cos 4 ,
c 7
On substituting it in eqn. (1), we get
v 4 4
v gR 1 gR
2 7 7
4
Therefore, speed of CM of cylinder just before it leaves the constant is gR .
7
(c) At the moment, when the cylinder leaves the constant,

4
v gR
7
Therefore, rotational kinetic energy,
1 2
KR I
2


2
1 1 v 1 2
Or K R mR 2 mv
2 2 R2 4
12. FBD of cylinder and block are as shown by Newton’s laws

40 – 2T – fs = 8a (1)
T – fs = 4a/2 (2)
Subtracting equation (2) from equation (1)
40 – 3T = 6a
T = (40 – 6a)/3
Also, by = I , we get
3a
T R + fs R= I
2R
T + fs = 3Ia/2R2
(40 – 6a)/3 + (40 – 12a)/3 = 3Ia/2R2 a = 80/(18 + 9I/2R2)
As = I = I (3a/2R)
=I =I (3a/2R)
3I 80 3 80 80
N m
2R 9I 18 9 9
18
2R 2
13. Before cutting string
After cutting string

By constraint that lower end will have acceleration only in horizontal direction.
from (i), (ii) and (iii)
14.
about O=0
H
ma mgr
4
F H
. gr
M m 4
F 4N
P s
N
15.
N mg
4R
P (R Rsin ) mg sin 0
3
3
Also sin s
4 3 s


16. mg 2T Ma
mr 2 a
2TR IX
2 R
Ma 2a
T And a
4 3
17. Let m be the mass of the disc. Then translational energy of the disc is
1
KT mv 2 When it ascends on a smooth track its rotational kinetic energy will
2
remain same while translational kinetic energy will go on decreasing. At highest point.
1 v2 (6)2
KT = mgh or mv 2 mgh or h 1.8 m .
2 2g 2 19
18. Comparing this with linear motion,

Power P = F.v
d
We have P = . or I P
d
2 P 1/3
or d d on integration, we find that
or (n) 1/3.
2r
19. Centre of mass of semicircular ring lies at a distance of from the center.
2r
OC , OP r
Hence, CP (OC) 2 (OP) 2
or CP = 1.185r.
If there is no slipping, then the instantaneous axis of rotation passes through P.
C
O I =2mr
mg N
f= N P
Angular acceleration of ring about P is

p (mg) (CO)
Ip (2mr 2 )


2r
(mg)
g
2
…(i)
(2mr ) r
Acceleration of center of mass,

a = (CP) ( )
g 1.185
(1.185r) g …(ii)
r
a C x
O
a y
a
P From Newton’s law,
Fy ma y
or mg - N = may
or mg - N = ma sin
1.185 2r 1
or mg N m g
1.185r
2
2
mg 0.2 mg
or N = mg - 0.2mg
or N = 0.8 mg …(iii)
Fx = max
or sN= (m) (a cos )
1.185g r
or s (0.8mg) (m)
1.185r
or s = 0.398
Therefore, minimum value of static friction is 0.398.
20. I system mA rA2 mB rB2 mA mB / mA mB r2
Lsystem I system m A mB / m A mB r2
2
IB mB rB2 mB m2A / mA mB r2
2
LB IB mB mA2 / mA mB r2
SS

CHEMISTRY
21. (b) Boron liberates hydrogen with alkali.
22. Both H2 and D2 show spin isomerism. Ortho-H2 has more m.pt and b.pt than Para-H2
both increase in temperature para convertes into Ortho. Due to opposite spins of
protons Para H2 has lesser internal energy than Ortho-H 2
23. (a) Lanthanide contraction.
(c) Due to large size of chlorine.
24. (b) 5CO I 2O5 5CO2 I2
25. Salts of aluminium suffer hydrolysis on heating.

26. Concept of silicates.
(d) Silicon has less tendency to form multiple bonds with oxygen.
27. (a) SiO2 is acidic, PbO2 is amphoteric and CO is neutral.
(c) LiHCO3 cannot exist in solid form.
28. Due to more rate of diffusion. H 2 will be adsorbed rapidly than D2 on solid surface.
Since O-D bond is polar while D-D bond is non-polar. So, exchange reactions with
D2O is eaiser. Atomic sizes of H 2 , D2 and T2 are same.
H 2 F2 H 2O
29. SiO2 NaOH Na2 SiO3 SiF4 H 2 SiO3 H 2 SiF6
30. Interstitial carbides are more denser and harder than pure metals.
31. A is C3O2 O C C C O
12
32. In cyclic silicate ion Si6O18 the number of oxygen atoms shared is 6.
33. The number of monovalent oxygen atoms are present in the mineral kinoite
Ca2Cu2 Si3O10 .2H 2O is 8.
34. Graphite, C6O , SiH 3 3

N ; AlCl3 monomer , H 3 BO3, layered BN, B3 N3H 6 (Borazine )
contain sp 2 hybrid atoms.

35. Al2O3 , SnO, SnO2 , PbO, PbO2
36. AlH 3 3 H 2O Al OH 3 3H 2
Al2O3 3C N2 2 AlN 3CO
AlN 3H 2O Al OH 3 NH 3


HCOOH CO
3CH 2 COOH 2 P4O10 3C3O2 4 H 3PO4
5CO I 2O5 I 2 5CO2
Fe2O3 3C 2 Fe 3CO
P4O10
CH 2 COOH 2
H 2O
37. All give Hydrogen gas.

38. Feldspars, Ultra marines, Zeolites
39. X = +2, Y = +4.
Conc. H 2 SO4
40. COOH 2
H 2O
CO CO2
Conc. H 2 SO4
HCOOH CO
H 2O
Al2O3 3C N2 2 AlN 3CO
K 4 Fe CN 6 3H 2 SO4 (dilute) 2 K 2 SO4 FeSO 6HCN
180o C
Ni CO 4 Ni 4CO
2 B2O3 7C B4C 6CO
MATHS
1 1 1 1
x x x x
e e e e
41. lim 1 1
1 and lim 1 1
1 , lim f x exists, if lim g x 0
x 0 x x x 0 x x x 0 x 0
e e e e
42. f x is continuous at ' x ' satisfying 5 x x 2 6 i ,e x 2, 3
43. Given f x . f y f x f y f xy 2 x, y R
Put x y 1 then f 1 2 3 f 1 2 0
f 1 1 or f 1 2
If f 1 1 then f x 1 x R.
A contradiction ( degree of f x is positive)
f 1 1 , hence f 1 2
1 1 1
Replace ' y ' with then f x . f f x f f 1 2
x x x


n
f x must be in the form x 1 or x n 1 .
f 4 65, f x x3 1 f1 x 3x 2
3
44. Plotting the graph we get points of discontinuity at x , , 0, and is continuous
2 2
3
at x , f x is not differentiable at x ,
2 2 2
cos x 0 x cos 1 3 4
45. f x 34 cos 1 3 4 x sin 1 3 4
sin x sin 1 3 4 x 2
f x is continuous for all x and is not differentiable at 2 points
46. lim f x lim f x f 5

x 5 x 5
25 6
1 5 b 1 3ab2 a ,b
108 5
1
47. f 1 lim x x x
x 1 x
lim x 0 x 1
x 1
1
1
f 1 lim x x x
x 1 x
lim x 1 x 0
x 1
1
1
f 2 lim x x x
x 2 x
lim x 0 x 2
x 2
4
1
f 2 lim x x x
x 2 x
lim x 0 x 1
x 2
2
48. Clearly for x 0 f x is differentiable.
At the point x 0 ,


f x f 0
f1 0 lim
x 0 x 0
x n sin 1 x
lim
x 0 x
lim x n 1 sin 1 x 0
x 0
f is differentiable at x 0 also, f is differentiable x
49. f 1000 f f 1000 1
f 1000 f 999 1
999 f 999 1
1
f 999
999
1
The numbers 999 and are in the range of f .
999
Hence, by intermediate value property of continuous function, function takes all
1
values between 999 and , then there exists
999
1
,999 such that f 500
999
1
Then f f f 1 f 500
500
1 1
Similarly, 199 ,999 , thus f 199
999 999
But there is nothing to show that 1999 lies in the range of f . Thus (D) is not correct
and (C) is also incorrect.
2 tan 1 x if x 1
1 2x
50. sin 2 tan 1 x if 1 x 1
1 x2
2 tan 1 x if x 1
f x is continuous for all x , and is not differentiable x 1,1
x
51. f x is not continuous at x 3, 6,9,12,15,18, 21, 24, 27
3
1 1
2sin x 2 tan x
52. K lim f x lim
0 2 tan x
x 0 x 2sin x


1 1 1
sin x tan x tan x
2 1 2
lim
x 0 2 tan x sin x
1 2sin x
1 1 1
2sin x tan x 1 sin 1 x tan 1 x 2tan x
lim 1
x 0 sin 1 x tan 1 x 2 tan x sin x 1 2sin x
tan x sin x
tan x sin x
53. lim f x f 0
x 0
ab 2 x2 3x
lim sin cos 1 3
x 0 x2 a b
2 9
ab 3
a 2b 2
4b 2 6b 9a 0
b is real, D 0 a 14
54. (i) f x 1 x 0
1 x 0
(ii) f x 1 x 0
1 x 0
(iii) f x 1 x 0
1 x 0
(iv) f x 1 x 0
1 x 0
(v) f x 1 x 0
1 x 0
(vi) f x 1 x 0
1 x 0
55. Draw the graph, we get the function is not differentiable and continuous at two points
between x 2 and x 2 also function is not continuous at x 2 and x 2
x 2 x 0
2
56. f x x 2 0 x 1
x x 1

x 2 if x 2
f x x 2 if -2<x 0
x2 2 if 0 x<1
x if x 1
Clearly f x is discontinuous at x 1
57. f x a sinx be x cx3 if x 0

x
a sinx be cx 3 if x 0
Clearly f x is continuous at x 0
a cos x be x 3cx 2 if x 0
f1 x
a cos x be x 3cx 2 if x 0
L.H.D=R.H.D
a b a b a b 0
n
x 1
58. lim 1
x 1 log e cos m x 1
n 1
n x 1
lim 1
x 1 sin x 1
m.
cos x 1
n 1
n x 1
lim 1
x 1 m tan x 1
n
1, n 2, m n 4
m
59. f 2x f x x
x x
f x f
2 2
x x x
f f
2 4 4
:
:
:
x x x
f n 1
f
2 2n 2n


x x x x
Adding f 2 x f x .... n
2n 2 4 2
x x x x
lim f 2 x f lim x .... n
n 2n n 2 4 2
x
f 2x 1
1
1
2
f 2x 2x 1
f x x 1
60. Conceptual


Sec: Jr. Super60-I Date: 07-10-17
2012_PAPER-II
CHEMISTRY: Detection of nitrogen, sulphur, phosphorus and halogens, Estimation of
carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus, Hybridisation of carbon; Sigma
and pi-bonds; Shapes of simple organic molecules
PHYSICS:
Sec – I(Q.N : 1 – 8) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 9 – 14) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Sec – III(Q.N : 15 – 20) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66
CHEMISTRY:
Sec – II(Q.N : 29 – 34) 3 -1 6 18
(3 Comprehensions : 3+3 = 6Q)
Total 20 66
MATHEMATICS:
Sec – I(Q.N : (41 – 48) Questions with Single Correct Choice 3 -1 8 24
Sec – II(Q.N : (49 – 54) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Total 20 66
PHYSICS Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. What is direction of gravitational field at a point P . P is on a plane containing biggest
circle of uniform hollow hemisphere as shown.
A) a B) b C) c D) d
2. Let magnitude of gravitational field at a distance r from centre of uniform
hemisphere of mass m at point p shown in figure be E . ( R is radius of hemisphere)
Gm Gm Gm Gm
A) E B) E C) E D) E 2
r2 2r 2 r2 r R
3. Gravitational field at a point p in a small hole made in uniform thin spherical shell of
mass m and radius R is approximately
Gm Gm Gm
A) B) C) 0 D)
R2 2 R2 3R 2
4. Gravitational field at point P due to rod of mass m is
2
Gm Gm Gm 1 1
A) B) 2
C) 2
D) Gm
r1r2 r1 r2 r1 r2 r1 r2
2
5. A wire of uniform cross sectional area ' a ' length l is having density which varies
linearly from p1 at one end to p2 at other end. Both ends of wire are connected and
wire is transformed into a circular loop. Length of wire doesn’t change. The
component of gravitational field along the axis of circular loop made of given wire at
a distance x from the centre of loop is
G p1 p2 al G p1 p2 lax
A) 2
B) 3
2x 2 2
l
x2
2
G p1 p2 lax G p1 p2 lax
C) 3
D) 3
2 2 2 2
l l
2 x2 2 x2
2 2
6. Gravitational field due to very long hollow cylinder of mass m, length l , and radius R
at a point on the axis of cylinder just outside cylinder is l R
2Gm Gm Gm 3Gm
A) B) C) D)
Rl Rl R2 Rl
7. Two uniform rods A and B of length 0.6 m each of masses 0.01 kg and 0.02 kg
respectively are rigidly joined end to end. The combination is pivoted at the lighter
end, P as show in figure. Such that it can freely rotate about point P in a vertical
plane. A small object of mass 0.05 kg moving horizontally, hits the lower end of the

combination and sticks to it. What should be the velocity of the object, so that the
system could be raised to the horizontal position
A) 6.3 m/s B) 8.2 m/s C) 4 m/s D) 9 m/s

8. A cubical block of side a moving with velocity v on a horizontal smooth plane as
shown. It hits a ridge at point o. The angular speed of the block after it hits o is
A) 3v/ 4a B) 3v /2a C) 3 v / 2a D) Zero

SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Questions 9 and 10
Three particles each of mass m can slide on fixed frictionless plane as shown in figure.
Particle m1 moves with velocity V0 and hits particle m2 , the coefficient of restitution
1
being e . Assuming that m2 and m3 are at rest initially and lie along a radial line
2
before impact and the spring is initially unstretched. Consider only one collision
between m1 and m2
9. The maximum velocity of m3 is

3 3 V0 V0
A) V0 B) V0 C) D)
5 10 2 5

10. The maximum stretch of the spring is
3 m V0 m V0 m 3V0 m
A) V0 B) C) D)
4 5k 4 k 4 3k 4 3k
Two skaters, each of mass 50kg, approach each other along parallel paths separated by
3m. They have equal and opposite velocities of 10ms 1 , The first skater carries a long
light pole 3m long and the second skater grabs the end of it as he passes on the
frictionless surface and the two skaters are connected by the pole
11. The angular velocity of the pole after the skaters are connected is
22 1 20 1 17 1 14 1
A) rads B) rads C) rads D) rads
3 3 3 3
12. By pulling on the pole, the skaters reduce their distance apart to 1 m. The angular
velocity now is
A) 45rads 1 B) 50 rads 1
C) 55 rads 1
D) 60 rads 1

A pair of stars rotates about a common center of mass. One of the stars has a mass
M and the other has mass m such that M = 2m. The distance between the centres of
the stars is d (d being large compared to the size of either star).
13. The period of rotation of the stars about their common centre of mass
(in terms of d, m, G.) is
4 2 3 8 2 3 2 2 3 4 2 3
A) d B) d C) d D) d
Gm Gm 3Gm 3Gm
14. The ratio of the angular momentum of the two stars about their common centre of
mass (Lm/ LM) and the ratio of kinetic energies of the two stars (Km/KM.) is
A) 1 & 1 B) 2 & 2 C) 2 & 9 D) 9 & 9

SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
15. Rod inclined at an angle with vertical strikes the horizontal frictionless ground.
0 . The angular velocity of rod before striking is zero & linear velocity v is
vertically downwards. Which of the following statements is / are correct?

A) Angular momentum of rod is conserved during collision about point of impact on
ground.
B) For elastic collision the centre of rod rebounds back with velocity v.
C) For elastic collision the centre of mass of rod rebounds back with velocity v.
D) For perfectly inelastic collision the velocity of centre of mass just after collision
becomes zero.
16. Mass of all the balls and uniform rod of length l is m and the system of balls
A, B, C and rod was initially at rest on horizontal frictionless ground. A, B, C are
touching rod but not sticking to it. Ball D collides with one end of rod
perpendicularly. Which of the following is correct statement about direction of motion
of small balls A, B, C , D & rod shown just after collision of ball D with rod?

A) A, B moves towards right just after collision

B) C moves left just after collision
C) D moves towards right just after collision
D) Centre of mass of Rod moves towards right just after collision
17. A thin ring of mass 2kg and radius 0.5 m is rolling without slipping on a horizontal
plane with velocity 1 m/s. A small ball of mass 0.1 kg, moving with velocity 20 m/s in
the opposite direction, hits the ring at a height if 0.75 m and goes vertically up with
velocity 10 m/s. Immediately after the collision
A) The ring has pure rotation about its stationary CM

B) The ring comes to a complete stop
C) Friction between the ring and the ground is to the left
D) There is no friction between the ring and the ground
18. A uniform bar of length 6 a and mass 8 m lies on a smooth horizontal table. Two point
masses m and 2m moving in the same horizontal plane with speed 2v and v
respectively, strike the bar [as shown in the figure] and stick to the bar after collision.
Denoting angular velocity (about the centre of mass), total energy and centre of mass
velocity by , E and vc respectively, we have after collision
3v v 3 2
A) vc 0 B) C) D) E mv
5a 5a 5
19. Two identical uniform rods connected end to end by a frictionless pin joint are placed
along x axis on a frictionless horizontal surface. These are free to rotate with respect
to each other about vertical axis z axis passing through pin joint. A particle of mass
m moving with velocity v along y axis strikes rod at one end as shown. The direction
of velocities of different points on rod just after collision will be
A) C along ĵ B) C along ĵ C) A along ĵ D) A along ĵ

20. Two heavy metallic plates are joined together at 90o to each other. A laminar sheet of
mass 30kg is hinged at the line AB joining the two heavy metallic plates. The hinges
are frictionless. The moment of inertia of the laminar sheet about an axis parallel to
AB and passing through its centre of mass is 1.2 kg – m2. Two rubber obstacles P and
Q are fixed, one on each metallic plate at a distance 0.5 m from the line AB. This
distance is chosen, so that the reaction due to the hinges on the laminar sheet is zero
during the impact. Initially the laminar sheet hits one of the obstacles with an angular
velocity 1 rad/s and turns back. If the impulse on the sheet due to each obstacles is 6
N – s. The location of centre of mass of laminar sheet from AB is x & angular velocity
of laminar sheet just after impact is . Values of x and are?
A) =0.1 rad/s B) =1 rad/s C) x =0.1 m D) x=0.2 m

CHEMISTRY Max. Marks: 66
SECTION – I
21. In Lassiagne’s test, the organic compound is fused with a piece of sodium metal in
order to
A) Increase the volatility of the compound
B) Decrease the melting point of the compound
C) Convert the ionic compound into a mixture of covalent compounds
D) Convert the covalent compound into a mixture of ionic compounds
22. During the test for halogens, sodium extract is heated with HNO3 . The reason for this
is
A) To decompose NaCN and Na 2S B) To make Na 2S soluble
C) To make NaCN soluble D) to make silver halides insoluble
23. An organic compound was analyzed by Duma’s method 0.546g of an organic
compound gave 38ml of nitrogen at 350K and 732 mm pressure . Calculate the
percentage of nitrogen in the compound (vapour pressure of water at 350K is 32 mm)
A) 6.25% B) 25% C) 12.5% D) 15%
24. Which of the following is the most electronegative carbon?
A) SP hybridised B) SP 2 hybridized
C) SP 3 hybridised D) all have equal electronegative
25. Allyl isocyanide [ CH2CHCH2NC ] has
A) 9 sigma and 4 pi bonds
B) 8 sigma and 5 pi bonds
C) 8 sigma, 3 pi and 4non-bonded electrons
D) 9 sigma, 3 pi and 2non –bonded electrons
26. Lassiagn’s test for the detection of nitrogen will fail in case of
A) NH 2CONH 2 B) H 2 NCONHNH 2 .HCl
C) H 2 NNH 2 .HCl D) C6 H5 NHNH2 .HCl
27. The number of tetrahedral bond angles present in methane?
A) 4 B) 2 C) 6 D) 8
28. In the Lassaigne’s test for nitrogen in an organic compound, the Prussian blue color is
obtained due to the formation of
A) Na4 Fe CN 6 B) Fe4 Fe CN 6 3
C) Fe2 Fe CN 6
D) Fe3 Fe CN 6 4

SECTION - II
This section contains 6 multiple choice questions relating to two paragraphs with three questions on each paragraph.
Paragraph for Questions 29 and 30:
During the estimation of nitrogen in an organic compound by Kjeldhal’s method, the
ammonia evolved from 0.5g of the compound, was .absorbed in 50ml of 0.5 M
H 2 SO4 . The residual acid required 60ml of 0.5M NaOH solution
29. What volume of H 2 SO4 is used by NH 3 in the process?

A) 50ml B) 10ml C) 20 ml D) 30 ml
30. The percentage of nitrogen in the compound is
A) 2.8 B) 56 C) 18.6 D) 14
Answer questions 31 and 32 based on the following structure.
H3C H
CH3
H
CHO

31. How many pure atomic orbital’s of carbon & hydrogen are involved in bond
formation in the above molecule?
A) 12 B) 9 C) 15 D) 16
3
32. How many sp hybridized carbon orbital’s are present in above molecule?
A) 4 B) 12 C) 8 D) 16
N, S, halogens and phosphorous present in an organic compound are detected by
Lassaigne’s test, by fusing the compound with Na metal. The compounds formed are
extracted from fused by boiling it with distilled water. This extract is known as
sodium fusion extract or Lassaigne’s extract.
33. Violet color in the detection of sulphur with sodium nitroprusside is due to the
formation of
A) Na3 Fe CN 5 NOS B) Na4 Fe CN 5 NOS
C) Na4 Fe CN 4 S D) Na2 Fe CN 5 S
34. An organic compound containing N, S, and O as extra elements is fused with metallic
sodium and then extracted with distilled water. Which species is not present in the
Lassaigne’s extract?
A) NO3 B) C N C) S CN D) S 2
SECTION – III
35. Which of the following compounds may give blood red coloration while performing
Lassaigne’s test for nitrogen?
A) (NH2)2CO B) (NH2)2C = S
SO3H
SO3H
NH2
C) D)
36. Kjeldahl’s method cannot be used for estimation of nitrogen in
A) C6H 5NO2 B) Pyridine
C) C6H5 – N = N – C6H 5 D) C6H 5NHCOCH3
37. Which of the following compounds will give white precipitate with AgNO3?
A) C6 H 5 N H 3 I B) NaCl
C) NH 2 N H 3Cl D) C6 H 5 N H 3Cl

2
38. Which has at least one sp hybridized carbon atom?
A) CH 2 C H B) H C C
C) H 2C C CH 2 D) O C C C O
39. Which of the following is the correct statement regarding ethene?
A) All the atoms are in the same plane
B) Bond provides the most reactive centre in the molecule.
C) SP 2 Hybridized carbon atoms are present
D) One C C bond is present
40. Which of the following is correct?
A) Oxidation state of Fe in sodium Nitro prusside is 2+
B) AgI is in yellow color due to polarization effect
C) AgBr is a yellow ppt. and is sparingly soluble in excess NH 4OH
D) Yellow ppt is the detection of phosphorus when an organic compound is heated
with Na2O2 and then boiled with con. HNO3 , followed by the addition of Ammonium
molybdate is NH 4 3 PO4 .12 MoO3

MATHS: Max. Marks: 66
SECTION – I
41. If y is a function of x and ln x y 2 xy , then y1 0
A) 1 B) -1 C) 2 D) 0
42. If be a repeated root of a quadratic equation f x 0 and A x , B x , C x be
polynomials of degree 3,4,5 respectively, then

A x B x C x
F x A B C is
1 1 1
A B C
2
A) not divisible by x B) divisible by x , not by x
2
C) divisible by x , not by f x D) divisible by f x
43. Let P x a0 a1 x a2 x 2 ..... an x n . If P x ex 1

1, x 0 , then the maximum
value of a1 2a2 3a3 ....... nan is

1
A) B) 1 C) n D) e
n
1
44. Let g x f 1
x and f is a bijective function such that f 1 x 4
, then g 1 x is
1 x
equal to
1 4 1 4 4
4
A) 1 g x B) 1 f x C) 1 f x D) 1 g x
x100 x99 x2
45. If f ( x) ... x 1 then
100 99 2
A) f 1 (1) f 1 (0) B) 100 f 1 (1) f 1 (0)
C) f 1 (1) f 1 ( 1) D) f 1 (1) 100 f 1 (0)

46. Suppose that f is differentiable function with the property
f x
f x y f x f y x 2 y 2 and lim 100 , then f 1 o is equal to
x 0 x
A) 100 B) 20
C) 30 D) none of these
d2 y
47. If x y y x c, then is
dx 2
2 2 2 2
A) B) 2
C) D)
c c c2 c

1 y
Tan
48. If x2 y2 ae x
;( a 0), ( y(0) ae 2 ) then y11 (0)
a /2 2 /2 a /2
A) e B) ae /2
C) e D) e
2 a 2
SECTION - II
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each paragraph.
Let y f x be a continuous function for 1 x 6 such that f 0 0 and
(1) The graph of f 1 x is made of line segments joined such that left end point is
included and right end point is excluded in each sub interval,

( f 1 x takes integral values)
(2) The graph starts at the point 1, 2 .
(3) The derivatives of f x , where defined, agrees with the step pattern as shown here.

Using the above information answer the following.

49. The range of f x is _____
A) 1,3 B) 0,3 C) 0,3 D) (0,3]
50. Number of integral roots of the equation f x 1 is
A) Exactly 3 B) exactly 4 C) exactly 2 D) none

Paragraph for Questions 51and 52
Let f : R R be a continuous and differentiable function such that
f x y f x .f y x, y , f x 0 and f 0 1 and f ' 0 2.
Let g xy g x .g y x, y and g ' 1 2; g 1 0

51. Identify the correct option
A) f 2 e4 ; g 3 9 B) f 2 2e 2 ; g 3 9
C) f 1 4; g 3 3 D) f 3 729 ; g 3 3
52. The number of values of x, where f(x)=g(x):
A) 0 B) 1 C) 2 D) 3
A function of the form x = f(t), y = g(t) where ‘t’ is a parameter, is called as a

parametric function, where f, g are differentiable functions of‘t’.Also it can be used
dy dx dy
that .Now answer the following questions on the basis of above
dx dt dt
information.
dy
53. If x 3cos cos3 , y 3sin sin 3 then = ------------ at
dx 4
2 1
A) B) – 1 C) D) 1
3 2
2
dy x2 4
54. x sec cos ,y sec6 cos 6 ; 2k 1 / 2, k Z , then dx y2 4
A) 36 B) 6 C) 30 D) None of these
SECTION – III
55. A twice differentiable function f(x) is defined for all real numbers and satisfies the
following conditions:
'
f (0)=2; and f "(0) 3.
The function g(x) is defined by g ( x) e ax f x x R, where ‘a’ is any constant.
If g ' 0 g" 0 0 then ‘a’ can be equal to:

A) 1 B) -1 C) 2 D) -2
56. Let f x be a non constant polynomial satisfying the relation
f x .f y f x f y f xy 2 for all real x and y and f 0 2 ,suppose
f 4 65 . Then
A) f 1 x Is a polynomial of degree 2
B) Roots of f 1 x 2 x 1 are real
C) xf 1 x 3 f x 1
D) f 1 1 3
d
57. If f x g x where g x e x. f x ex. f x then
dx
given f 0 0 .
A) g x Is an even function
B) f x is an odd function
C) g 1 0 f1 0 g 0
D) g1 0 f 0
x sin x3 x dy
58. If y e tan x then may be equal to:
dx
x sin x3 x
A) e 3x3 cos x3 sin x3 tan x ln tan x 2 x cos ec 2 x
x sin x3 x
B) e x3 cos x3 sin x3 tan x ln tan x 2 x cos ec2 x
x sin x3 x
C) e cos x3 x3 sin x3 tan x ln tan x 2 x cos ec2 x
x sin x3 x x s ec 2 x
D) e 3 x3 cos x 3 sin x 3 tan x ln tan x
tan x

59. Let g x lnf x where f x is twice differentiable positive function on 0,
such that f x 1 x f x then for N 1, 2, 3, ......... ; g N 1 g 1 .....

2 2
1 1 1
A) 41 ....... 2
9 25 2N 1
1 1 1
B) 4 1 ....... 2
9 25 2N 1
1 1 1
C) 41 ....... 2
9 25 2N 1
1 1 1
D) 4 1 ....... 2
9 25 2N 1
60. If f x y , f x f y and f x y are in A.P x, y R ;f 0 0 then
A) f 4 f 4
B) f 2 f 2 0
C) f 4 f 4 0
D) f 2 f 2


KEY SHEET
2012-P2
PHYSICS
1 C 2 C 3 B 4 A 5 C
6 B 7 A 8 A 9 B 10 A
11 B 12 D 13 D 14 D 15 A
16 CD 17 AC 18 ACD 19 BD 20 BC
CHEMISTRY
21 D 22 A 23 A 24 A 25 D
26 C 27 C 28 B 29 C 30 B
31 C 32 D 33 B 34 A 35 BC
36 ABC 37 BCD 38 AC 39 ABCD 40 ABCD
MATHS
41 A 42 D 43 B 44 D 45 D
46 A 47 C 48 C 49 C 50 C
51 A 52 B 53 B 54 A 55 AD
56 ABCD 57 AB 58 AD 59 A 60 AC
SOLUTIONS
PHYSICS
1. Conceptual
2. Conceptual
3. Net Gravitational field
Field due to local surface
Field at hole = (Net Gravitational field) – (Field due to local surface)

Gm
2R2
4.
Gdm G dr
E
r2 r2
1 1 G r2 r1 Gm
G E
r r2 r1r2 r1r2
p1 p2 al l
5. m R
2 2
Gm
E 3
R2 x2 2
6. Conceptual

7. System is free to rotate but not free to translate. During collision, net torque on the
system (rod A+ rod B+ mass m) about point P is zero. Therefore, angular momentum
of system before collision = angular momentum of system just after collision
(about P). Let be the angular velocity of system just after collision, then
Li Lf mv 2l I Here. I= moment of incrtia of system about p

2
2 2 l2 l
m 2l mA l / 3 mB l Given, l 0.6 m, m 0.05 kg , m A
I2 2
0.01kg and mB 0.02 kg . Substituting the values, we get I 0.09 kg m 2
Therefore, from Eq. (i)
2 mvl 2 0.05 v 0.6

I 0.09
0.67v
Now, after collision, mechanical energy will be conserved. Therefore, decrease in rotational KE
= increase in gravitational PE
1 2 l 1
or I mg 2l mA g mB g l
2 2 2
2 gl 4m mA 3mB
or
I

9.8 0.6 4 0.05 0.01 3 0.02
0.09
2
17.64 rad / s
4.2 rad / s
Equation Eqs. (ii) and (iii), we get
4.2
v m / s or v 6.3 m / s
0.67
8. Conservation of angular momentum
ma 2 ma 2 mva
6 2 2
1
a 1 v
3
3v
4a
9. Conservation of angular momentum during collision of m1 & m2
m1V0 2 R m1V1 2 R m2V2 2 R
V0 V1 V2 1
V0
V2 V1 2
2
3V0 3V0
2V2 V2
2 4
By conservation of angular momentum when the masses will have same
3V0
m R 5mR 2
2
3V0
R
10
max imum speed of m3
2
1 2 1 1 3V0
10. kx 5mR 2 2
m
2 2 2 4
mV02
x
80 k
11. Conceptual
12. Conceptual
13. Let the angular speed of revolution of both stars be w about the common centre ,
that is, centre of mass of system.
The centripetal force on star of mass m is
2 2d Gm 2m 4 2 3
m . Solving we get T d
3 d2 3Gm
14. The ratio of angular momentum is simply the ratio of moment of inertia about
center of mass of system.
2
2d
m
Lm Im 3
2
2
LM IM d
2m
3
Similarly, The ratio of kinetic energy is simply the ratio of moment of inertia about
center of mass of system.
2
1 2
2d
Im m
Km 2 3
2
2
KM 1 2 d
IM 2m
2 3
15. Conceptual
16. Conceptual
17. The data is incomplete. Let us assume that friction form ground on ring is not
impulsive during impact. From linear momentum conservation in horizontal direction.
We have
2 1 0.1 20 = 0.1 0 2 v
Here, v is the velocity of CM of ring after impact. Solving the above equation, we
have v = 0 Thus CM becomes stationary.
Correct option is (a).

Linear impulse during impact
(i) In horizontal direction
J1 p 0.1 20 2 N s
(ii) In vertical direction
J2 p 0.1 10 1N s
Writing the equation (about CM)
Angular impulse = Change in angular momentum We have,
3 1 1 2 1
1 2 0.5 2 0.5
2 2 2 0.5
Solving this equation comes out to be positive or anti-clockwise. So just after

collision rightwards slipping is taking place. Hence, friction is leftwards. Therefore,
option (c) is also correct. Correct options are (a) and (c)
18. Pi 0
Pf 0 or vC 0
Li L f or 2mv a 2mv 2a I ........... i

2
8m 6a 2
Here, I m 2a 2m a 2 30 ma 2
12
v
Substituting in Eq. (i), we get
5a
2
1 2 1 2 v 3mv 2
Further, E I 30 ma
2 2 5a 5
Correct options are (a), (c) and (d).
19. Conceptual
20. Let r be the perpendicular distance of CM from the line AB and the angular
velocity of the sheet just after colliding with rubber obstacle for the first time.
Obviously the linear velocity of CM before and after collision will be
vi r 1rad / s r and v f r . vi and v f will be in opposite directions.
Now, linear impulse on CM

= change in linear momentum of CM
or 6 m v f vi 30 r r
1
or r 1 ………….(i)
5
Similarly, angular impulse about AB = change in angular momentum about AB
Angular impulse = Linear impulse
Perpendicular distance of impulse from AB
Hence, 6 0.5 m I AB 1
(Initial angular velocity = 1 rad/s)
or 3 I CM Mr 2 1
or 3 1.2 30r 2 1 …………(ii)
Solving Eqs. (i) and (ii) for r, we get

r = 0.4 m and r = 0.1 m
But at r = 0.4 m, comes out to be negative (-0.5 rad/s)
Which is not acceptable. Therefore,
(a) r = distance of CM from AB = 0.1m
(b) Substituting r = 0.1m in Eq. (i), we get = 1 rad/s ie, the angular velocity with
which sheet comes back after the first impact is 1 rad/s.
(c) Since, the sheet returns with same angular velocity of 1 rad/s, the sheet will never
come to rest.
CHEMISTRY
21. To convert the covalent compound into a mixture of ionic compounds
22. NaCN and Na 2S decomposes into HCN and H S
2
23. VN 2 38ml
P 732 32 700
700 38 273
VN2 at STP ml
350 760
22400ml 28 gm N 2
2 38 273 28 2 38 273
gm
760 22400 760
28 2 38 273 100
% Nitrogen = 6.25%
22400 760 0.546
24. SP SP 2 SP3
25. CH 2 CH CH 2 N C:
26. NH 2 NH 2 .HCL
27. 6
28. Fe4 Fe CN 6 3
29. / 30. The residual acid requires, 60 0.5 meq of NaOH = 30meq NaOH
The no.of meq of H 2 SO4 that reacts with NH 3 = (50 1 30) 20meq
no.of meq of NH 3 is 20 meq
Weight of NH 3 = 20 10 3 17g
= 0.34g
Weight of Nitrogen in 0.34g NH 3 is 0.28g
0.28
% by weight of N 100 56%
0.5
31. Conceptual
32. Conceptual
33. Na2 Fe CN 5
NO Na2 S Na4 Fe CN 5
NOS
34. CN , CNS , S 2
2
35. Fe3 SCN Fe SCN
36. Nitro compounds, Pyridine and azo compounds

37. AgCl
38. Conceptual
39. NCERT - 327
40. NCERT

MATHS
1
41. 1 y1 2 xy1 y Put y 0
x y
42. F1 0 F x is divisible f x
43. P1 x a1 2a2 x 3a3 x 2 .... nan x n 1

ex 1
Put x 1 a1 2a2 ... nan 1
44. f g x x f 1 g x g1 x 1
1 4
g1 x 1
1 g x
f g x
45. Conceptual
f' x
46. Observe f 0 0 and Lt 100 f' 0 100
x 0 1
Now using first principle
f x h f x f x f h x 2 h2 f x
f' x Lt Lt
h 0 h h 0 h
f h
Lt 0
h 0 h
f' 0 100
47. Conceptual
48. Take ‘log’ and differentiate twice and use y ' 0 1
49. f x 2x a : 1 x 0
b:0 x 1
x c :1 x 4
x d :4 x 6
50. a b 1 x, 4 c d 4
f 0 0 a 0 b, c 1, d 7
f x 2x : 1 x 0
0:0 x 1
x 1:1 x 4
7 x:4 x 6

51. & 52.
f(x)=e2x
g(x)=x2
dy
d dy
53 cot 2
dx dx
d
dx
54. Tan sec cos Tan x2 4
d
dy
6Tan sec 6 cos 6 6Tan y2 4
dx
dy 6 y2 4 dy
2
x2 4
36
dx x2 4 dx y2 4
55. g’(x)=aeax+f’(x) g’(0)=a-5

g”(x)=a2eax +f”(x) g”(x)=a2+3
a=-2,1
1
56. Put y to get f x 1 x3
x
57. g x g x and f ' x g x
g x is even and f is odd
x sin x3 x
58. e 3 x3 cos x3 sin x 3 tan x ln tan x 2 x cos ec 2 x
x sin x3 x x s ec 2 x
e 3x3 cos x3 sin x3 tan x ln tan x
tan x
59. g x 1 g x ln x differentiable twice and put x 1 , 3 , 5 ,.... 2N 1

2 2 2 2
60. 2f x f y f x y f x y
f x cos x is suitable function
Since f 0 0


Sec: Jr. Super60-I Date:14-10-17
2016_PAPER-I
CHEMISTRY: ORGANICCHEMISTRY-Nomenclature of Hydrocarbons, Nomenclature of
mono and bi-functional organic compounds including common names, Nomenclature of
Aromatic compounds (Benzene), Structural isomerism (excluding Tautomerism)

PHYSICS:
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62
CHEMISTRY:
Sec – II(Q.N : 24 – 31) 4 -2 8 32
Total 18 62
MATHEMATICS:
Sec – II(Q.N : 42 – 49) 4 -2 8 32
Total 18 62

PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. The gravitational potential energy of interactions of a system of six identical particles,
each of mass m placed at the vertices of a regular hexagon of side ‘a’ is [PE = 0 at
infinite separation]
Gm 2 1 1 3Gm 2 1 1
A) 1 B) 1
a 3 4 a 3 4
6Gm 2 1 1 2Gm 2 1 1
C) 1 D) 1
a 3 4 a 3 4
2. An un powered spacecraft has to hit a far off planet of mass M, radius R. Maximum
entrance area h 2 from which ‘the spacecraft can be projected so as to hit the planet.
Size of the spacecraft is negligible compared to planet

GM 2GM
A) R2 1 2
B) R2 1 2
RV0 RV0
2GM 2GM
C) 4 R 2 1 2
D) 4 R 2 1 2
RV0 RV0
3. If a satellite is revolving around a planet of mass M in an elliptic orbit of semi-major

axis a, the orbital speed of the satellite when it is at a distance r from the focus.
2 1 2 1
A) V 2 GM B) V 2 GM
r a r2 a
2 1 2 1
C) V 2 GM D) V 2 G
r3 a2 r a
4. A shell of mass M and radius R has a point mass m placed at a distance r from the
centre. The gravitational potential energy U (r) vs r will be [assume potential energy at
infinity to be zero]
A) B)
C) D)
5. A uniform hollow sphere has internal radius a and external radius b. The ratio of
gravitational potential at a point on its outer surface to that of a point on its inner
surface is
2 b3 a 3 2 b3 a 3 a a 2 b2
A) B) C) D) 1
3b b2 a 2 3b b2 a2 3b a 2 b 2


SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
6. A satellite is orbiting the earth in a circular orbit of radius r. Its
1
A) kinetic energy varies as 1/r B) angular momentum varies as
r
1 1
C) linear momentum varies as D) frequency of revolution varies as
r r 3/2
7. A double star system consists of two stars having masses M and 2M. The distance
between their centres is equal to r. They revolve under their mutual gravitational
interaction. Then, which of the following statements are not correct.
A) Heavier star revolves in circular orbit of radius 2r/3
B) Both the stars revolve with same angular speed, period of which is equal
2
to r 3/ 2
3GM
C) Kinetic energy of the heavier star is twice that of the other star.
GM 2
D) Kinetic energy of the heavier star is
3r


8. A satellite of mass m orbits around the Earth in an elliptical path of semi-major and
semi-minor axis 2a and a respectively such that the Earth is located at one of the foci
of the elliptical path. At an instant when the satellite is located at a distance of r , its
velocity is u at an angle of 600 with respect to the position vector of the satellite from
the centre of the Earth. Consider only the gravitational force between the satellite and
the Earth and assume that the Earth is a perfect sphere.
(Assume that mass of the satellite is negligible as compared to mass of the Earth)
A) Orbital angular momentum of the satellite with respect to centre of the Earth is
3
mur
2
B) Areal velocity of position vector of the satellite with respect to centre of the Earth
3
is ur
4
8 a2
C) Time period of orbital motion of the satellite around the Earth is
3 ur
D) Time period of satellite’s orbital motion is independent of mass of the Earth


9. Inside a uniform sphere of mass M (M is mass of complete sphere) and radius R, a
R
cavity of radius is made in the sphere as shown. Then
3
A) Gravitational field inside the cavity is uniform.

B) Gravitational field inside the cavity is non-uniform
88GM
C) The escape velocity of a particle projected from point A is
45R
D) Escape velocity is defined for earth and particle system only.
10. A tunnel is dug along a chord of non-rotating earth (hypothetical) at a distance d as
shown. A small block is released from rest in the tunnel from the surface of earth. The
block comes to rest at the centre C of tunnel. If is the coefficient of friction between
block and tunnel then

C
R
d
2
3GMm
A) The work done by the friction on the block is
8R
3
B)
2
1
C)
2
D) The gravity does +ve work on block
11. Assuming Earth, an uniform sphere of mass M and radius R. At a point P inside Earth
at a distance r measured from centre of Earth (r < R)
3 r 2 Gm
A) Pressure (p) caused by gravitational compression is 1
8 R 2 R3
3 r 2 GM 2
B) Pressure (p) caused by gravitational compression is 1
8 R2 R4
3 GM
C) Gravitational field Intensity at the centre is
2 R2
D) Gravitational field Intensity at the centre is zero.


12. If a body is projected with speed lesser than escape velocity:
A) the body can reach a certain height and may fall down following a straight line
path
B) the body can reach a certain height and may fall down following a parabolic path
C) the body may orbit the earth in a circular orbit
D) the body may orbit the earth in an elliptic orbit
13. Orbital velocity of a satellite revolving around a planet in a circular orbit depends on
A) Mass of the satellite
B) Mass of the planet
C) Radius of the orbit
D) angular velocity of rotation of the planet
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
14. Assuming V as the gravitational potential at the centre of earth, the potential at a
11V
distance half the radius from its centre will be . The value of x is
10 x


15. Gravitational potential versus distance r graph is represented in fig. The magnitude of
gravitational field intensity is equal to X (N/Kg). Then find X
16. A particle is projected vertically upwards from the surface of the earth (radius Re)
with a speed equal to one fourth of escape velocity. The maximum height attained by
Re
it from the surface of the earth is . Then 'N' is
5N
17. Two uniform solid spheres of equal radii R, but mass M and 4M have a centre to
centre separation. 6R, as shown in the figure.


The two spheres are held fixed. A projectile of mass ‘m’ is projected with minimum
velocity from the surface of the sphere of mass M directly towards the centre of the
second sphere so that it reaches the surface of the second sphere. If the speed with
xGM
which the projectile reaches the surface of the sphere of mass 4M is 3 find x
5R
18. A bullet is fired vertically upwards with velocity v from the surface of a spherical
planet. When it reaches its maximum height, its acceleration due to the planet’s
gravity is 1/4th of its value at the surface of the planet. If the escape velocity from the
planet is vesc = v N , then the value of N is (ignore energy loss due to atmosphere)


CHEMISTRY Max Marks: 62
SECTION – I
19. The IUPAC name of the following compound is
CH3
OH
H3C CH3
A) 2,6-dimethylhepta-2,5-dienoicacid.
B) 3,7-dimethylhepta-2,5-dienoicacid.
C) 1-Hydroxy-2,6-dimethylhepta-2,5-dienone
D) 3-Hydroxy -2,6-dimethylhepta-2,5-dienone.
20. Some statements about structural isomers of C5 H11 Br are given below.
i) It has four primary bromides
ii) It has three secondary bromides
iii) It has two tertiary bromides.


iv) It has one tertiary bromide.
Select the correct ones..
A) i, ii B) i, ii,iv C) ii, iii D) iii
21. Which of the following compounds have both aldehydic and etheric functional
groups?
o o o
o o o
o
i) o ii) iii) iv)
A) i, iii B) ii, iii C) i, iv D) i, ii, iii
22. Which of the following pairs are correctly matched ?
A) n-butylchloride and iso-butyl chloride are positional isomers.
B) n-pentylalcohol and neo-pentyl alcohol are functional isomers.
C) n-propylmethanoate and ethylethanoate are metamers
D) ortho-dichlorobenzene and meta-dichlorobenzene are chain isomers
23. Identify the correct statement among the following
A) The number of monochloroderivatives for propane (ignore stereoisomers) is three.
B) The number of dichloroderivatives for propane(ignore stereoisomers) is three.
C) The number of trichloroderivatives for propane(ignore stereoisomers) is five.
D) The number of monochloroderivatives for isobutane(ignore stereoisomers) is
three.

SECTION – II
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
24. Which of the following pairs are functional isomers?
A) Acetaldehyde and acetone
B) Propanenitrile and ethyl isocyanide
C) diethylamine and Butanamine
D) Ortho-methylphenol and Benzylalcohol
25. Which of the following compounds having four structural isomers?
A) C4 H 9 Cl B) C4 H10 O C) C4 H11 N D) C3 H 9 N
26. Which of the following given IUPAC names are not correct?
CH 3
CH CHO
A) :Formylethylbezene
CH 2 CH CH
B) CHO CHO :Propene-1,3-dicarbaldehyde


CH 2 CH CH 2 Cl
C) Cl CH 2 Cl :1,3-dichloro-2-chloromethylpropane
D) :1-methyl-3-ethylcyclohexene
27. Metamerism can be shown by
A) Ketones B) Esters C) Ethers D) tertiary amines
28. The correct names of functional isomers of butanoicacid is/ are
A) Ethylethanoate B) Methylpropanoate
C) Propylmethanoate D) Isopropylmethanoate
29. Identify the correct statement/s among the following is/are
A) N,N-dimethylaniline and Phenylmethyl amine are functional isomers.
B) N-methylaniline and phenylethanamine are functional isomers.
C) iso-butylamine and tertiarybutyl amine are chain isomers.
D) n-butylamine and iso-butylamine are chain isomers.
30. Which of the following names are correct for the compound containing molecular
formula is C7 H 8 O ?
A) Phenylmethanol B) 2-methylphenol
C) 3-methylphenol D) methoxybenzene.

31. Select the correct combination/s among the following is/are
A) Ortho-cresol : 2-methylphenol.
B) Catechol : Benzene-1,3-diol.
C) Resorcinol : Benzene-1,2-diol.
D) Hydroquinone : Benzene -1,4-diol
SECTION – III
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases
32. No of metamers from the following molecules whose molecular formula is C6H 12O
is/are........
CH 3 CO CH CH 3
CH 3 CH 2 CO CH 2 CH 2 CH 3
CH 3
CH 3 CH 2 CO CH CH 3
CH 3 CH 2 CH 2 CH 2 CH 2 CHO
CH 3
CH 3 CH CH 2 CH 2 CHO
CH 3 CO CH 2 CH 2 CH 2 CH 3
CH 3
CH 3 CO CH CH 2 CH 3 CH 3 CO CH 2 CH CH 3
CH 3 CH 3
CH 3 CH 3 CH 3
CH 3 CO C CH 3 CH 3 C CO C CH 3
CH 3 CH 3 CH 3


33. The number of structural isomers of C4 H10 O is ‘X’ and for C2 H 6 O is ’Y’.
Then the X + Y is..
34. The number of correct IUPAC names for the given compounds is..
i) CH 3 CH CH CH 2 C C CH 3 : hept-2-en-5-yne.
ii) CH 2 CH CH 2 C CH : pent-1-en-4-yne.
iii) CH 3 CH CH CH 2 C CH : hex-4-en-1-yne.
iv) CH 2 CH CH 2 C C CH 3 :hex-5-en-2-yne.
v) CH 3 3 C CH CH C CH 3 3
:1,2-di( 30 -butyl)ethene.
NC CH 2 CH CH 2 CN
vi) CN : propane -1,2,3-tricarbonitrile.
CH 2 CHO
vii) : benzeneacetaldehyde.
35. The number of structural isomers possible for C6 H 6 O3 containing benzene ring
(Do not consider peroxybond containing isomers) is X.
The number of structural isomers possible for C7 H 9 N containing benzene ring is Y.
Then X + Y is....
36. The number of cyclic isomers for C5 H10 is ‘X’ and the number of open chain structural
isomers for C5 H10 is ‘Y’. Then X Y is..


MATHEMATICS Max Marks: 62
SECTION – I
37. If 3x 2 y 1 acts as a tangent to y f x at x 1 / 2 and if
x x 1
p lim 2x 2x
then, pr _______
x 0 e e r 1
f f
2 2
A) 1/2 B) 1/3 C) 1/6 D) 1/7

38. If the equation x5/3 5 x 2/3 K has exactly one positive root, then, the complete
solution set of K is,
A) , B) ,0 C) 3, D) 0,
39. A sphere of radius 10cm shrinks to radius 9.8cm. The approximate decrease in volume
is ____ cu.cm
A) 80 B) 80 C) 16 D) 16


2
ax
40. If the point on y x tan ,0 where the tangent is parallel to y=x has
2u cos 2
2
2
u2
an Ordinate then the value of is
4a
A) B) C) D)
2 6 3 4
41. A horse runs along a circle with a speed of 20km/h. A lantern is at the centre of the
circle. A fence is there along the tangent to the circle at the point at which the horse
starts. The speed with which the shadow of the horse moves along the fence at the
moment when it covers 1/8 of the circle in km/h is
A) 20 B) 40 C) 30 D) 60
SECTION – II
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
42. Which of the following curves are orthogonal
x2 y 2 x2 y2 x2 y2 x2 y2
A) 1, 1 B) 1, 1
21 17 3 1 47 4 21 23
x2 y2 x2 y2 x2 y2 x2 y2
C) 1, 1 D) 1, 1
49 4 23 22 21 9 42 30

x
43. Points on the curve f x , where the tangent is inclined at an angle of to x
1 x2 4
axis are
3 2 3
A) 0, 0 B) 3, C) 2, D) 3,
2 3 2
44. The family of curves defined by the equations y ax and x 2 y 2 c 2 are

perpendicular for
A) a 2, c 4 B) a 2, c 3 C) a 3, c 2 D) a 3, c 2
45. The normal to the curve y 2 5 x 1 at the point 1, 2 is of the form ax 5 y b 0

then
A) a = 4 B) b = – 14 C) a + b = – 10 D) ab = 40
46. Two motor cars start with the same velocity ‘v’ km/hour from distances ‘a’ km and
‘b’ km from the junction of two roads inclined at 900 and travel towards the junction
and after 2 hours, they are nearing each other at the rate of
4v 2 a b v 2v 2 a b v
A) 2 2 2
km / hour B) 2 2
km / hour
a b 4 a b v 8v a b 2 a b v 8v 2
6v 2 a b v 8v 2 a b v
C) 2 2 2
km / hour D) 2 2
km / hour
a b 6 a b v 8v a b 8 a b v 8v 2

47. The radius of a right circular cylinder increases at the rate of 0.1 cm/min, and the
height decreases at the rate of 0.2 cm/min. The rate of change of the volume of the
cylinder, in cm3/min, when the radius is 2 cm and the height is 3 cm, is

8 3 2
A) 2 B) C) D)
5 5 5
48. A point on the parabola y 2 18x at which the ordinate increases at twice the rate of
the abscissa is
9 9 9 9
A) (2, 6) B) (2, – 6) C) , D) ,
8 2 8 2
49. An error of 0.01cm is made while measuring the radius 5cm of a circle.
A) The error in circumference will be 0.02 cm
B) The error in area will be 0.1 sq.cm
C) The relative error in circumference will be 0.002
D) The percentage error in area will be 0.004


SECTION – III
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases
50. Water is dripping out from a conical funnel of semi vertical angle at the uniform
4
rate of 2cm3 / s .Through a tiny hole at the vertex at the bottom when the slant height
of the water is 4cm. If cm / s be the rate of decreases of the slant height of the water,
then the value of 4 2 must be
51. The rate of change of the volume of a sphere with respect to its surface area, when the
radius is 2 cm, is
52. If y 4 x 5 is tangent to the curve y 2 px3 q at the point (2, 3) then p q =
53. If the normal to the curve y f x at x 0 be given by the equation 3x y 3 0 , then
1 1
the value of lim x2 f x 2 5 f 4 x2 4 f 7x2 is then k=
x o k
54. A man 1.6m high walks at the rate of 30m per minute away from a lamp which is 4m
above ground. If k is the rate at which the man‘s shadow is lengthening, then the value
of k/4 is _____________


KEY SHEET
2016-P1
PHYSICS
1 C 2 B 3 A 4 D 5 A
6 ACD 7 AC 8 ABC 9 AC 10 ABD
11 BD 12 ABCD 13 BC 14 2 15 8
16 3 17 3 18 2
CHEMISTRY
19 A 20 B 21 C 22 C 23 C
24 BCD 25 AD 26 ABD 27 ABCD 28 ABCD
29 D 30 ABCD 31 AD 32 6 33 9
34 4 35 8 36 0
MATHS
37 A 38 D 39 A 40 C 41 B
42 AC 43 AD 44 ABCD 45 ABC 46 A
47 D 48 CD 49 ABCD 50 2 51 1
52 9 53 3 54 5
SOLUTIONS
PHYSICS
1. Total potential energy is V Uij
Gm 2 1 1 1 6Gm 2 1 1
6 6 3 1
a a 3a 2a a 3 4
2.
r B
R V
LCAM mv0 r mVR

v0 r
V
R
1 2 GMm 1 2
L.C.E mv0 mv
2 R 2
v02 GM 1 v02 r 2
2 R 2 R2
v02 R 2GM R
r2
v02
R2 2 2GM
Area = r 2 v0
v02 R
3. As in case of elliptic orbit of a satellite mechanical energy E=-(GMm/2a) remains

constant , at any position of satellite in the orbit,
1 2 GMm GMm 2 1
Therefore mv , i.e, v 2 GM
2 r 2a r a
4. Potential inside a shell is constant

5.

1 2 GmM 1
6. Kinetic energy mv or KE . Thus choice (A) is correct.
2 2r r
GM
Angular momentum = mvr = mx xr m GMr , which is proportional to r .
r
Hence choice (B) is wrong.

GM 1
Linear momentum mv = m , which is proportional to . Hence choice (C) is
r r
1 1 GM 1
correct. The freuqeuncy of revolution is v 3
.i.e. v 3/ 2 .
T 2 r r
Hence the correct choices are (A), (C) and (D)

7. A) The centre of mass of the double star system remains stationary and both the stars
revolve around in circular orbits which are concentric with the centre of mass
Mr 2M.0 r
The distance of centre of mass from the heavier star is equal to
M 2M 3
Hence, the heavier star revolves in a circle of radius r/3 while the lighter star in a
circle of radius 2r/3. Hence option(a) is wrong.
r 2
B) (2M) 2GM 2
3
1/ 2 1/ 2
r 2 2GM 2 3GM 3GM r 3/ 2
(2M) T 2
3 r2 r3 T r3 3GM
1/2
Where r is distance between two stars. Hence, option (b) is correct.

C) Kinetic energy of a star will be equal to 1/2 mv2 where v is speed of the star which
is equal to (radius of its circular orbit) x .
Hence, K.E. of heavier star is
2
1 r Mr 2 2
3GM GM 2
E1 (2M)
2 3 9 r3 3r
2
1 2r
And that of lighter star, E 2 M .
2 3


It means, KE of the lighter star is twice that of the heavier star.
Hence, option (C ) is wrong.
0 3mur
8. A) L m u cos30 r 2
dA L 3ur total area 2 a2 8 a2

B) dt 2m 4 C) T areal velocity 3ur 3ur
4
3
M 4 R M
9. Mcavity
4 R 3 3 3 27
3
At ' A ' Vtotal Vcavity Vremaining
M
G
GM 27 9
Vremaing
R 5R
3
GM GM 44GM
VR
R 45R 45R
For escape velocity
1 44GMm
mv 2
2 45R
88 GM
V
45 R
10. Work done due to friction is given by

GMm R2 GMm
W 3
3R 2
2R 4 R
GMm 11R 2 GMm 3GMm

2 R3 4 R 8R
GMm 2 d
dW x R2 dx
R3 x 2
R2
GMm
d dx
2R2
GMm 3 R /2
W x
2R2 0
GMm 3R GMm
3
2 R2 2 4R


GMm 3GMm 3
3
4R 8R 2
11. Inward gravitational pull on the layer
GM 3M
df .r (4 r 2 p.dr ), P
R3 4 r3
df R 3 r 2 GM 2
dp ,P dp 1
4 r2 r 8 R2 R4
12. (A) If it is projected radially it will go up and than move down in a straight line
B) If it is projected will a small velocity near the earth`s sarface, g will be almost
constant So its path will be almost parabolic. (Projectile Motion)
GM
(C) If the body is projected tangentially with orbital speed V0 then it will
r
revolve in circular orbit

(D) If the body is projected with a velocity V (Vo,Ve) it may revolve in an elloptical
orbit.
13. Conceptual
3GM GM
V , Vat r 3R 2 r2
14. 2R 2R 3
R 11GM 11 2V 11V
at r
2 8R 8 3 12
dv
15. E here dx drSin
dx
1 1 2GM GMm GMm R

16. m. h
2 4 R R R h 15
GMm G 4 Mm GMm G 4 Mm 1 3GM
17. mV 2 V 3
2R 4R 5R R 2 5R
1
18. At height R from the surface of planet acceleration due to planet’s is th in
4
comparison to the value at the surface
GMm 1 2 GMm GMm 1 2
So, mv and mvesc 0
R 2 R R R 2
vesc v 2


CHEMISTRY
2 1 OH
O
5
19. 7
20. It has 4 primary, 3 secondary and one tertiary bromides.

21. i and iv have aldehydic and etheric groups
22. Different alkyl groups connected to same functional grops are called metamers.
23. For A is 2, for B is 4, for D is 2
24. Acetaldehyde and acetone are non isomers (molecular formula is not same)
25. A has four isomers(n-butyl, sec. butyl, isobutyl and ter. butyl chlorides)
B has seven structural isomers (four alcoholic and three etheric)
C has 8 structural isomers (primary amines =4 ,sec. Amines =3 , ter. Amine = 1)
D has 4 structural isomers (propanamine -1 ,propanamine-2 ,N-methylethanamine and
trimethyl amine.)
26. A (2-phenyl propanal) B) pent-2-en-1,5-dial D)4-ehtyl-2methylcyclohexene-1
27. all can show metamerism
28. A) CH 3COOC2 H 5 B) CH 3 CH 2 COOCH 3
C) H COOCH 2 CH 2 CH 3 D) H COOCH (CH 2 )CH 3
29. A) are not isomers
C) are positional isomers
30. All are correct
CH 2 OH OH OH OCH 3
CH 3
A) B) C) CH 3 D)
OH OH
CH 3 OH
31. ortho cresol- : Catechol-


OH
OH
Resorcinol: OH : Hydroquinone- OH
32. ii, x are not isomers for the given compound and iii and v are aldehydes:
33. X= 7 and Y= 2
34. i, ii, iii, vi are correct.
OH
OH OH
OH
OH
OH , OH OH
35. X is 3( , OH )
NH 2
CH 2 NH 2 NH CH 3 NH 2 NH 2
CH 3
CH 3 CH3 )
Y is 5( , , , ,
36. X=5( , , , , )
Y = 5( , , , , )
MATHS
3
37. Sol. slope of 3x 2y 1 is
2
1 3
f1
2 2
x x 1 0 1 1
p lim 2x 2x
x 0 e e 0 1 1 3
f f f1 f1
2 2 2 2
1 1 1/ 3 1/ 3 1
pr .....
r 1 3 32 1 1/ 3 2/ 3 2
38. Sol. Sketch y x5/3 5x2/3 and y K


ax tan 1
40. Sol. Given m=1 tan 1 x u 2 cos 2 substitute x and
u cos 2
2
a
u2 u2 1
y values in given equation sin 2
4a a 2 3
42. Conceptual
1
53. Put x
2
t , and f '(0) 3


2013_PAPER-II
CHEMISTRY: Geometrical isomerism, Conformational isomerism of ethane, butane, derivatives of
ethane and cyclohexane
Sri Chaitanya IIT Academy 21-10-17_Jr.Super60-I_JEE-Adv_2013_P2_WAT-22_QP

IIT-JEE-2013-P2-Model
PHYSICS
Sec – I(Q.N : 1 – 8) Questions with Multiple Correct Choice 3 -1 8 24
Sec – II(Q.N : 9 – 16) 3 -1 8 24
(4 Comprehensions – 2 +2+2+2 = 8Q)
Sec – III(Q.N : 17 – 20) Matrix Matching Type 3 -1 4 12
Total 20 60
CHEMISTRY
Sec – I(Q.N : 21 –28) Questions with Multiple Correct Choice 3 -1 8 24
Sec – II(Q.N : 29 – 36) 3 -1 8 24
Total 20 60
MATHEMATICS
Sec – I(Q.N : 41 – 48) Questions with Multiple Correct Choice 3 -1 8 24
Sec – II(Q.N : 49 – 56) 3 -1 8 24
Total 20 60
SEC: Jr. Super60-I space for rough work Page 2


PHYSICS Max.Marks:60
SECTION – I
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
1. The physical quantities having same units are
A) mass and moment of inertia per unit area
B) pressure and energy density
C) Moment of force and torque
D) Linear momentum and angular momentum
2. If U, m L and G denote energy, mass, angular momentum and universal gravitational

m 5G 2
constant, respectively. The dimensions of are same as
UL2
A) co-efficient of restitution B) refractive index
C) solid angle D) distance


x
3. If y a 3 sin 1
1 , where y is in metre. Then,
b
1
A) the dimensions of a is M 0 L3T 0
1 x
B) the unit of sin 1 is radian
b
C) the dimensions of x are same as those of b
D) the unit of a is metre
1
4. The speeds of two particles are measured to be v1 10.20 0.02 ms and
v2 6.40 0.01 ms 1 . Then, mark the correct options(s).

1
A) The sum of speeds of particles is 16.60 0.03 ms
1
B) The difference of speeds of particles is 3.80 0.03 ms
1
C) The difference of speeds of particles is 6.40 0.01 ms
1
D) The sum of speeds of particles is 16.60ms


5. If y sin , the error in measurement of is 10 . The fractional error in y
A) may be zero
B) may be infinity
C) will have any value from zero to infinity
D) must be zero
6. A student uses a simple pendulum of exactly 1 m length to determine g, the

acceleration due to gravity. He uses a stopwatch with the least count of 1 s for this and
records 40 s for 20 oscillations. For the observation, which of the following statements
(s) is/are correct?
A) Error T in measuring T, the time period is 0.05 s
B) Error T in measuring T, the time period is 1 s
C) Percentage error in the determination of g is 5%
D) Percentage error in the determination of g is 2.5%


7. Out of the following expressions for couple per unit twist (C), time period (T) of a
compound pendulum, time period T 1 of a simple pendulum and frequency (f) of a
stretched wire respectively, the dimensionally consistent equations are

( = length, F = Force, A = area, = angle, r = radius)
r4
A) C (here F/A )
2
K2
B) T 2 here K radius of gyration
g
C) T1 2
g
1 T0
D) f here linear density , T0 =tension in string
8. If the dimension of the length are expressed as G x c y h z , where G, c and h are the
universal gravitational constant, speed of light and Planck’s constant respectively, then
A) x 1/ 2, y 1/ 2 B) x 1/ 2, z 1/ 2
C) y 1/ 2,z 3/ 2 D) y 3/ 2, z 1/ 2

SECTION - II
This section contains 4 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
A small spherical ball suspended from a rigid support using inextensible and light
string and free to oscillate without friction is called a simple pendulum. The time
L
period of small oscillation of simple pendulum is given by T 2 .
g
C
Here, L = Distance between suspension point O and centre C of the ball,
g = Acceleration due to gravity.
In the determination of value of acceleration due to gravity g by simple pendulum, the
time period is measured by a stopwatch whose least count is 0.5 s and the length of
string is measured with a meter scale, having least count of 1 mm. The diameter of the

bob is measured with the vernier calipers with least count 0.01 cm. The following
observations are recorded.
i. Length of the string = 105.3 cm ii. Diameter of the bob = 2.45 cm
iii. Time period = 2.07 s iv. Number of oscillations = 10
9. Find percentage error in calculation of acceleration due to gravity.
A) 3% B) 4.9% C) 9.8% D) 0.28%
10. If we increase the number of oscillations from 10 to 20, find the new percentage error
in calculation of g.
A) 2.6% B) 4.9% C) 9.8% D) 6%
Paragraph for Question 11 and 12
The time period of simple pendulum is given by T k x g y where k is the constant of
proportionality, is the length of pendulum and g, the acceleration due to gravity, x
and y are dimensionless constants.
11. In the above equation, dimensions of and g are respectively
2
A) L , MLT B) L , L 2T
2
C) L , LT D) L 1 , LT 2


12. If the given equation is dimensionally correct then
1 1 1
A) x 1, y B) x ,y
2 2 2
1 1 1
C) x ,y D) x 1, y
2 2 2
In a new system of units, let the units of force, energy and velocity be 10 N, 0.1 J and
100 m/s respectively. In this new system,
13. the unit of length is
A) 0.50 m B) 1.00 m C) 10-3 m D) 10-2 m
14. the unit of mass is
A) 10-5 kg B) 10-3 kg C) 10-4 kg D) 10-2 kg
The energy ‘E’ of a particle varies with time t according to the equation
t
x
E E0 sin t e ; where x is displacement from mean position. E0 is energy at
infinite position and & are constants of appropriate dimensions.
15. Dimensional formula of is
A) M 0 L0T 1
B) M 1L0T 0 C) M 0 L 1T 0 D) M 0 L0T 0


16. Dimensional formula of is
A) M 1L0T 0 B) M0 L 1T 0 C) M 0 L0T 1
D) M 0 L0T 0
SECTION – III
(MATRIX MATCH TYPE)
This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists
have choices (A), (B), (C), and (D) out of which ONLY ONE is correct.
17. Considering Force (F), Velocity (V) and Energy (E) as fundamental quantities, match
the correct dimensions of following quantities
Column I Column II
I. Mass P. [F–1 V° E1]
II. Light year Q. [F1 V1 E–1]

1
III. Frequency R. [F3 V° E–2]
T
IV. Pressure S. [F° V –2 E1]

Codes
I II III IV I II III IV
A) S P Q S,R B) S P Q R
C) P Q P,Q P,S D) P,Q R,S R,S R,S

18. Match the Column I with Column II and mark the correct option from the given
below.
Column I Column II
If m,g, and I denote mass,
acceleration due to gravity, length
In the dimensional formula of
and moment of inertia,
I. P. defined quantity, the dimension of
respectively. The formula of
mass is 1
mgl
B
I
If , F and denote length, force
and linear mass density, In the dimensional formula of
II. respectively. The formula of Q. defined quantity, the dimension of
F time is (-2)
C 2
G = universal gravitational In the dimensional formula of

III. R.
constant. Me, Re are mass and defined quantity, the dimension of


radius of earth. The formula of length is zero
GM e
V
Re
If U and V represent potential

energy and velocity of a particle The dimensional formula of
IV. respectively, The formula of S.
defined quantity is ML0T 0
U
R
V2
Codes
A) Q,R R Q P,S B) P,R Q,R Q,S P,S
C) P,Q,R P,Q Q,R P,S D) Q,R R Q,S P,R


19. Match the following columns and mark the correct option from the codes given below.
Column I Column II
1
I. P. 1
3
1.00
II. Q. 0.3
3.00
III. 2 0.3 R. 0.33
IV. 2 0.6 S. 2
Codes
A) Q R S P B) P Q R S
C) Q,R Q,R P,S P,S D) Q R P S


20. During determination of acceleration due to gravity by simple pendulum in repeated
experiments, following observations are obtained.
2
S. No. of observations Acceleration due to gravity in ms
1 9.85
2 9.76
3 9.91
4 9.79
5 9.78
Match the following columns and mark the correct option from the codes given below.
Column I Column II
I. Mean value of acceleration due to gravity in ms 2 P 0.05
II. Mean absolute error in ms 2 Q 9.82
III. Relative error R 0.51

IV. Percentage error S 0.0051
Codes:
A) Q P S R B) Q P R S
C) Q R S P D) P Q S R

CHEMISTRY Max.Marks:60
SECTION – I
21. Identify the structure (s) that represent a conformation of 2,2-dimethylbutane sighting
along any C-C bond
A) P B) S C) Q D) R


22. For which of the following pairs of compounds are the CORRECT notation given?
Ph
N N
Ph Ph
Ph
N N
A) Z azobenzene E azobenzene
OH
H3C H3C
C=N C=N
H OH H
B) E acetaldoxime Z acetaldoxime
H COOH H H
C=C C=C
H COOH
NH2 NH2
C) Trans-o-amino cinnamic acid Cis-o-amino cinnamic acid
H3C CH2-CH2-CH3 CI-CH2 CH3

C=C C=C
H CH3 Br-CH2 C2H5
D) Z-isomer E-isomer


23. Which statement is/are right regarding
CI CH3
CH3 CH3
C=C & C=C
CH3 CI CI CI
I II
A) They are geometrical isomers

B) They are diastereoisomers
C) I is E-isomer and II is Z-isomer
D) They are conformers
24 Which of the compounds shown below are isomers?
A) B)
C) D)


25. Which of the following molecules are E-isomer?
B)
Me
F
A)
CI Me
CH3
H
CH3 CI
C) D)
H CH3
H H
26. Consider the following conformations of 3-Aminopropanal, amongst the given

conformations (P,Q,R,S) one of them is most stable.
CHO CHO
CHO
CHO
H H NH2 H
H NH2 R)
Q) S)
P)
H H H
H H
H H H H H
H NH2 H NH2


The correct statements for the above are:
A) H-bonding is present in the most stable conformer
B) Gauche conformation is the most stable conformer
C) Anti conformation is the most stable conformer
D) larger groups being separated by maximum distance in the conformer
27. Which of the following compounds can exhibit geometrical isomerism?
A) H 3C CH 2 CH CH CH 3 B)
H3C OH
H3C OH
C = N
C) H D) H3C CH3
28. In the Newmann projection for 2,2- dimethylbutane

X
H3 C CH3
H H
Y
X and Y can respectively be

A) H and H B) H and C2H5 C) C2H5 and H D) CH 3 and CH 3


SECTION - II
Cyclohexane exist as two chair conformations in rapid equilibrium at room
temperature. Each carbon atom on a cyclohexane ring has one axial and one equatorial
hydrogen. Ring flipping converts axial H’s to equatorial H’s and vice-versa.
In substituted cyclohexane, groups larger than hydrogen are more stable in the
equatorial position. The cis isomers has two groups on the same side of the ring, either
both up or both down. The trans isomer has two groups on opposite side of the ring,
one up and one down.


29. Find out most stable substituted cyclohexane among the following:
A) B)
C) D)
30. Find out most stable conformer of cis-3-fluorocyclohexanol
A) B)
C) D)

Geometrical Isomerism
Molecules having same molecular formula but differing in the orientation of atoms in
a space due to resistricted rotation.
31. Compound which do not exhibit geometrical isomerism
A) diethyl ether B)2-butene
C) 3,4- dimethyl-3-hexene D) 2-chloro-3-methyl-2-pentene
32. Which molecule is in “E” configuration

CH3
CH3 F CI
C=C C=C
CH3
A) CH3 B) I Br
COOH C2H5 CH3

CHO
C=C C=C
C) CI OH D) CI H


Stereoisomers, which can be interconverted simply by rotation about sigma bonds, are
conformational isomers. While those, which can be converted only by breaking and
remaking of bonds and not simply by rotation, are called configurational isomers.
The angle between C – C and C – H bonds on adjacent carbon atoms in any
conformation is called dihedral angle. The cyclic compounds most commonly found in
nature containing six membered rings can exist in a conformation that is almost
completely free of strain. The most stable conformation of cyclohexane is chair form.
According to Bayer strain theory, the greater is the deviation from the normal
tetrahedral angle, greater is the angle strain or torsional strain and hence lesser is the
stability of the cycloalkane.
33. Dihedral angle between two methyl groups of n-butane in the gauche and anti forms
respectively are:
A) 600, 00 B) 600 and 1800 C) 00, 600 D) 1800, 600
34. Which among the following conformation of cyclohexane is the most stable form?
A) Chair form B) Half chair form
C) Twist boat form D) Boat form

Those stereoisomers are called configurational isomers if they differ in spatial
arrangement of atom or group and are not interconvertible without cleaving a bond.
Geometrical isomerism arises due to restricted rotation about a bond or centre. The
number of G.I. is 2n where n = number of double bonds or rings or both. In some cases
the number of G.I. is less than 2n , where either side nomenclature will be possible.
35. Which of the following compounds can show geometrical isomerism?
Br CI
C
C
CH = C = CH - CH3
A) Br Br B) CH3
H 3C CH3
CH = C H 3C
CH3 CH3
CH3 H
C) H3C D) H3C
36. The number of G.I. of the compound
C2 H 5 CH CH CH CH CH CH CH 3 is
A) 4 B) 3 C) 8 D) 6

SECTION – III
(MATRIX MATCH TYPE)
37. Match the conformers of n-Butane along C2 C3 bond in Column I with torsional
energies given in Column II
Column I Column II
CH3
H H
I. P. 18.4 – 25.5 KJ/mol
H H
CH3
CH3
H
II. Q. 14.2 KJ/mol

H
H CH3
H


CH3
CH3
III. R. 3.3 KJ/mol

H
H H
H
CH3
H CH3
IV. S. Zero
H H
H
I II III IV
A) P Q S R
B) Q R P S
C) S Q P R
D) P Q R S


38. Match the following compounds from Column I with number of Geometrical Isomers
from Column II
Column I Column II
I. CH 3 CH C CH CH 3 P. 4
II. CH 3 CH CH CH N OH Q. 8
III. CH 3 CH C C CH CH 3 R. 0
IV. CH 3 CH CH CH CH CH CH C2 H 5 S. 2
I II III IV
A) S P R Q
B) R P S Q
C) Q R S P
D) P Q R S


39. Match the following compounds in Column I with type of isomerism in Column II
Column I Column II
(Molecule) (Most stable conformer)
I Ethane P Gauche
II Ethylene Glycol Q Anti
3-Fluoropropanal about
III R Staggered
C 2 C3
IV n-Pentane about C2 C3 S Fully eclipsed
I II III IV
A) R S P Q
B) Q R P S
C) R P P Q
D) P Q R S

40. Match the following compounds in Column I with their properties from Column II
Column I Column II
R R
HO H H R
I.
H OH
< H OH
P. Torsional strain
R OH
II. Q. Melting point
III. R. Dipole moment
IV. S. Boiling point
A) P Q R S B) Q P R S
C) S Q P R D) R S P Q

MATHEMATICS Max.Marks:60
SECTION – I
41. Let f : 0, 0, be a derivable function and F x is the primitive of f x
such that 2 F x f x f 2 x for any real positive x.
f x
A) f is strictly increasing B) lim 1
x x
C) f is strictly decreasing D) f is non-monotonic
42. Let f : R R be defined as f x sin x ax b a, b, R . Then the equation
f x 0 has :
A) only one real root which is positive if a 1, b 0
B) only one real root which is negative if a 1, b 0
C) only one real root which is negative if a 1, b 0
D) only one real root which is positive if a 1, b 0


2
43. Let f be a real –valued function on R defined as f x x 4 1 x , then which of
the following statement (s) is (are) correct ?
A) f ' c 0 for some c 0,1
B) f " x vanishes exactly twice in R.
C) f x is an even function
2
D) Monotonic increasing in 0, 1,
3
44. For which of the following functions Rolle’s theorem is applicable ?
x 2
A) f x ,x 1, 4
2 x
B) f x x 1 x 3/ 2 , x 0,1
3
C) f x x 1 ,x 2,0
5 1
D) f x sgn x sgn x ,x , (sgn (x) denotes signum functions) of x)
2 2

45. Let f x be a twice differentiable function such that f " x 0 in 0,2 . Then :
A) f 0 f 2 2 f c for atleast one c 0,2
B) f 0 f 2 2f 1
C) f 0 f 2 2f 1
2
D) 2 f 0 f 2 3f
3
2 3
46. Let h x f x f x f x for every real number x. Then
A) h is increasing whenever f is increasing

B) h is increasing whenever f is decreasing
C) h is decreasing whenever f is decreasing
D) h is decreasing whenever f is increasing
47. In 0, Rolle’s theorem is applicable to
sin x
,x 0
A) f x sin x B) f x x
1, x 0
C) f x cos2 x D) f x sin 2 x sin x


a0 a1 a2 a
48. if ....... n 1 an 0 then a0 x n a1 x n 1
...... an 1 x an 0 has
n 1 n n 1 2
A) no solution in 0,1 B) at least one solution in 0,1
C) exactly one solution in 0,1 D) at least one solution in 2,3
SECTION - II
4 2
Consider, f x 2 x 3cos x, R.
49. The least positive integral value of for which f x is monotonically increasing for
all x R.
A) 2 B) 3 C) 4 D) 5
50. For 2, if f x x2 f sin x , then the sum of all integral values of x, is:
A) 3 B) 5 C) 6 D) 10


2
Consider a cubic, f x ax 3 bx 2 cx 4, a, b, c R and f " 0 and tangent
3
2 5x 100
drawn to the graph of the function y f x at x is y
3 3 27
51. The value of a b c is equal to:
A) 4 B) 6 C) 7 D) 10
d
52. If g is the inverse of f , then g x .f g x at x = 4 is equal to :
dx
1 4 3 4
A) B) C) D)
4 7 4 3
2
Consider, f x cos 2 x 2 x 2 1 1 x2 , R.
53. For 1, if f 3x 2 2 x 1 f x 2 2 x 9 , then number of integral values of x in
10,10 :
A) 3 B) 5 C) 16 D) 18


54. If f x is increasing for all x R, then number of values of
A) 1 B) 2 C) 3 D)
Let f ' sin x 0 and f " sin x 0 x 0, and g x f sin x f cos x
2
55. which of the following is true in 0, ?

2
A) g ' is increasing B) g ' is decreasing
C) g ' is non-increasing D) g ' is neither increasing nor decreasing
56. which of the following is true ?
A) g (x) is decreasing in ,
4 2
B) g (x) increasing in 0,
4
C) g x is monotonically increasing
D) None of these

SECTION – III
(MATRIX MATCH TYPE)
57. Match the column
For the function f(x) = ax2 – b|x|
Column – I Column – II
(A) f(x) has local max. at x = 0 (p) When a > 0, b > 0
(B) f(x) has local min at x = 0 (q) When a > 0, b < 0
b
(C) f(x) has local extremum at x (r) When a < 0, b < 0
2a
(D) f(x) is not diff. at x = 0 (s) When a < 0, b > 0
A B C D
A) Q,R S,R P,S P,Q,R,S
B) P,S Q,R P,R P,Q,R,S
C) P,R,S Q,R P,Q P,Q,R,S
D) P,S P,Q Q,R P,Q,R,S


58. Observe the following list
Column I Column II
A. f x x 2 2 x 5 is increasing in P.
x
B. f x e is increasing in Q. ,1 2,
C. f x log e x increasing in R. 1,
x3 3x 2
D. f x 2 x 5 is increasing in S. 0,
3 2
T. R
A B C D
A) R P S Q
B) P R Q S
C) Q R S P
D) S Q P R

59. Observe the following lists
Column I Column II
1
A. f x x is decreasing in P. R
x
1
B. f x 1 x 3 is decreasing in Q. 0,
e
C. f x xe x is decreasing in R. 1,0 0,1
D. f x x x is decreasing in S. 1,
The correct matching for list -I from list -II
A B C D
A) R S Q P
B) Q R P S
C) R P S Q
D) Q R S P


x x
60. Let f x 2 1 2 2 and g x 2sin x cos 2 x in 0,
Column I Column II
A. f increases on P. log2 3/ 2 ,
B. f decreases on Q. ,log 2 3/ 2
0,
C. g decreases on R. 6
5
D. g increases on S. ,
6
A B C D
A) R P Q S
B) Q S R P
C) P Q S R
D) S R Q P

Sec: Jr. Super60-I WAT-22 Date: 21-10-17
Time: 07:30 AM – 10:30 AM 2013_P2 Max.Marks:180
KEY SHEET
PHYSICS
1 ABC 2 ABC 3 ABC 4 AB 5 ABC
6 AC 7 ACD 8 BD 9 B 10 A
11 C 12 B 13 D 14 A 15 A
16 B 17 B 18 A 19 A 20 A
CHEMISTRY
21 CD 22 ABC 23 ABC 24 BCD 25 ABD
26 AB 27 ABC 28 BD 29 C 30 A
31 A 32 D 33 B 34 A 35 B
36 C 37 C 38 B 39 C 40 D
MATHS
41 AB 42 ABC 43 AD 44 ABCD 45 BD
46 AC 47 ACD 48 B 49 A 50 C
51 B 52 D 53 A 54 A 55 A
56 D 57 B 58 A 59 C 60 C
Sri Chaitanya IIT Academy 21-10-17_Jr.Super60-I_JEE-Adv_2013_P2_WAT-22_KEY &SOL’S

SOLUTIONS
PHYSICS
kgm 2
1. a) MASS kg I mr 2 kgm 2 I / A kg
m2
energy kgm 2 / sec2
b) Pressure F / A N / m2 , kg / m sec2
volume m3
kgm / sec2 kg
m2 m sec2
c) moment of force = force x distance = time
d) p kgm / sec L kg m / sec m kgm 2 / sec
Vrel sin i
2. e , , A / r2
urel sin r
2
5 Nm 2
kg
m5G 2 kg 2
2
UL2 N m kg m / sec m
kg 5 N 2 m 4 sec2
4
kg N m kg 2 m 2 m2
kg kg m / sec 2
dimensionless
kg 2 m 2
1 x
3. a) Here, sin 1 is dimensionless
b
1 x
b) Let sin 1
b
x
sin 1
b
Here, should be in radian.
1 x
So, the unit of sin 1 is radian
b
x
c) Dimensions of Deminsions of 1 = deimensionless
b
Dimension of x= Dimension ob b
Sec:Jr.Super60-I Page 2

4. a) Sum v1 v2 10.20 0.02 6.40 0.01
1
16.60 0.03 ms
b) Difference v1 v2 10.20 0.02 6.40 0.01
3.80 0.02 0.01

1
3.80 0.03 ms
dy
5. y sin or cos
d
Or dy cos d
Or y cos
y cos cos
Or
y y sin
y
Fractional error in y
y tan
But tan has any value from zero to infinity. Hence, fractional error will have any
value from infinity to zero. Hence, options (a) , (b), (c). are correct.
40 s
6. T 2s
20
Further, t = nT = 20T or t 20 T
t T
t T
T 2
Or T t 1 0.05s
t 40
l 1/ 2
Further, T 2 orT g
g
T 1 g
100 100
T 2 g
Percentage error in determination of g is
T 200 0.05
100 200 5%
g T 2
Correct options are (a) and (c).

7. a) is consistent, C is torque per unit twist, is modulus of rigidity, r is radius, is
length
b) is inconsistent, T is time period, k is the radius of gyration, g is acceleration due to
gravity
c) is consistent
d) is consistent, f is frequency, T is tension is mass per unit length
2 x 1 y 1 z
8. L M 1L3T LT ML2T
x z 0,3x y 2 x 1, 2 x y z 0
x 1/ 2, y 3/ 2, z 1/ 2
L 4 2L
9. T 2 g
g T2
2.45
105.3 106.5 25cm
2
T 2.07s
2 L
g 4
T2
g L 0.1 0.005 2 0.5
2
g L 106.525 2.07 10
0.00098 0.048 0.04898 0.049
g
Percentage error in g 100 0.049 100 4.9%
g
g 2 0.5
10. 0.00098 0.026
g 2 20.07
g
percentage error in calculation of g is 100 0.026 100 2.6%
g
11. and g are the length pendulum and the acceleration due to gravity. Hence, their
respective dimensions are L and LT-2
12. We have,
T k1x g y .... I
Writing dimensions on both sides of eq. (I), we get

2 y
T Lx LT
Or M 0 L0T M 0 Lx y T 2y
Equating exponents of M, L and T on both sides, we get

x y 0
And 2 y 1
1 1
Solving, y and .
2 2
13. force = 10N energy = 0.1J velocity = 100m/sec
Limit of surface
2 x y 1 z
L F x E yv Z MLT ML2T 2
LT
x y 0 x 2y z 1 2x 2 y z 0
x y 2 y 2y z 2 y 2 y2z
1
y 2y 0 1 L 10 0.11 1000 10 2
2 x 2 y 1 z
14. M MLT MLT LT
x y 1 x 2y z 0 2x 2 y z 0 x 0
1
M 100 0.1 100 2
15. LT should be dimensionless M 0 L0T 1

T M 0 L0T 0
16. x should be dimensionless M 0 L0T 1

L M 0 L0T 0
17. Conceptual
2
mgl MLT L 2
18. (i) B 2
T
l ML
Thus, i q, r
2
F MLT 1
(ii) C T
l2 ML 1
L 2
Thus, ii r
M 1 L3T 2
(iii) V M º L2T 2 , Thus, iii Q

L

ML2T 2
(iv) R ML º T º
1 2
LT
Thus, iv p, s
1
19. a) i 0.333 0.3
3
Thus, i q
1.00
ii 0.333 0.3
3.00
Thus, ii r
iii 2 0.3 2 0 2
Thus, iii s
iv 2 0.6 2 1 1
Thus, iv p
g1 g 2 g3 g4 g5
20. i
g 5
9.85 9.76 9.91 9.79 9.78 2
9.82ms
5
Thus, i q
2
ii g1 g1 g 0.032ms
2
g2 g2 g 0.060ms
2
g3 g3 g 0.090ms
2
g4 g4 g 0.030ms
2
g5 g5 g 0.040ms
g1 g2 g3 g4 g5 2
g 0.05ms
5
Thus, ii p
g 0.05
iii Re lativeerror 0.0051
g 9.82
Thus, iii s
g
iv Percentage error 100 0.51
g
Thus, iv r

CHEMISTRY
21. CONCEPTUAL
22. CONCEPTUAL
23. Geometrical isomers are diasteromers
Me Me
H OH HO Me
I) HO H II) HO H
24. Me H
25. As per CIP same priority groups on opposite gives E-isomer and same side Z-isomers
26. 1) Stable due to H- bonding 2) P is most stable due to H-bonding in it’s gauche
conformations.
27. CONCEPTUAL
28. Structural formula 2,2-dimethylbutane is
CH3
4 3
CH3 C CH2-4CH3
CH3
(I) Newman projection using C1 C2 bond

CH3
CH3 2 CH
3
1
H H
CH3
(II)Newman projection using C3 C2 bond

CH3
CH3 2 CH3
3
H H
CH3
29. In stable conformation, larger group occupies equatorial position

30. Due to H-bonding, structure (A) is most stable
31. To exhibit geometric isomerism, compound must has unsaturation or compound must
be cyclic with at least two different groups
32. Same priority groups are on opposite side

0 0
33. 60 and 180
34. Chair form is the most stable form
35. Allenes with even number of carbons are not planar & do not show G.I.
36. 2n 23 8
37. CONCEPTUAL
38. No of geometrical isomers = 2n
39. CONCEPTUAL
40. trans - compound has higher melting point than cis – compound. cis - compound is
more polar and hence has higher boiling point
MATHS
2
2 f x
41. f n 02 f x f x f x F x f x
2
F' x f x f' x f' x
But f ' x f x
f x 1
f' x 1 0
1 f x 1 f x
f is strictly increasing
f x f' x f x
Lt Lt dt 1
x x x 1 x 1 f x
As Lt f x
x
42. f :R R and f x sin x ax b f ' x cos x a

if a 1, then f is increasing
If a 1 then f is decreasing
If a b, f 0 b and b o f 0 0
y shown in the diagram

f x 0 has only the +ve root hence a is correct
If f 0 0 again f has only one negative root
If a 1, b 0 then f is decreasing
2
43. f x ,x 1 x
f' x 2 x 3 x 1 3x 2
f' x 0 x 0,2 / 3,1
f" x 2 x 2 15 x 2 2ox b
f" 0 0 and 15 ax 2 20 x b 0 has two roots

44. CONCEPTUAL
45. X 0, 2 and f " x 0
f ' x is increasing in 0,2
LMVT is and applicable let c1 0,1 and c2 1,2
f 1 f 0
By LMVT, f ' c1
1 0
f 2 f 1
f ' c2
2 1
f ' x is increasing and c1 c2
f ' c1 f ' c2
f 1 f 0 f 2 f 1
f 0 f 2 2f 1
Let c1 0,2 / 3 and c2 2 / 3,2
f'1 f' 2
f 2/3 f 0 f 2 f 2/3
2 2 23
0
3
2f 0 f 2 3 f 2/3

2 3
46. h x f x f x f x
2
h' x 3 f x 2f x 1 f' x
2
3 f x 2f x 1 0, x R
h' x 0 if f ' x 0
h is increasing whenever f is increasing
h' x 0 if f ' x 0
h is decreasing whenever f is decreasing
47. CONCEPTUAL
48. CONCEPTUAL
4 2
PASSAGE I f x 2 x 3 is x, R
4 2
49. f' x 2 3sin x 0
4 2
1 sin x 1 2 3 0
x 3 or 3
Least positive integer 2
f' x 16 8 3sin x 8 3sin x 0
f is increasing
50. f x x2 f sin x
x x2 sin x
x 1,2,3 respectively
sin x 1 2 3 6
PASSAGE II
f x ax 3 bx 2 cx 4
2
f' 2/3 5 / 3, f " 0
3
Degree of f ' x is two f " x is are
2
f' x k x 2/3 c

f' 2/3 c 5/ 3
2
k 2
f' x x 5/3
2 3
3
k 2 5x
f x x b
2 3 3
2 10
But f 0 b
3 9
2 5 100
And y 2/3
3 3 27
100
b
27
But coefficient x 3 1
3 5 100
f x x 2/3 x
3 27
x 3 2 x 2 3x 4
a 1, b 2, c 3
51 .a b c 6
1
52. g f and f g x x
d d
g x g x g x .x
dx dx
x. g ' x g x
atx 4, the derivative
4. g ' x g x
1
4. 0
3
1 1
Hence f 4 0 g x and g ' x 1
f 0
PASSAGE III
2
f x cos2 x 2 x 2 1 1 x2, R
53. 1 f x cos2 x 2 x

f' x 0 f is increasing
3x 2 2 x 1 x 2 2 x 9
2 x 2
x 1,0,1
2
54. f is increasing x R f' x 2sin 2 x 2 2 1 1 / 2x 0
1
at ,f' x 0
2
this is valid only at 1
55. f ' sin x 0 and f " sin x 0 x 0, / 2
g x f sin x f cos x
g' x f ' sin x cos x f ' cos x sin x
g" x f " sin x .cos2 x sin x sin x
g" x 0 g " x is increasing
56. g' 0 g' x 0, for x ,

4 4 2
and g ' x 0 for x 0,

4
g is increasing in ,
4 2
g is decreasing in 0,
4
57. CONCEPTUAL
58. CONCEPTUAL
59. CONCEPTUAL
60. CONCEPTUAL

2015_PAPER-I
CHEMISTRY: Optical isomerism, Inductive effect
Sri Chaitanya IIT Academy 28-10-17_Jr.Super60-I_JEE-Adv_2015_P1_WAT-23_Q'P
Time: 3:00 Hours IMPORTANT INSTRUCTIONS Max Marks: 264
PHYSICS:
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 18) Questions with Multiple Correct Choice 4 -2 10 40
Matrix Matching
Sec – III(Q.N : 19 – 20) 8 -4 2 16
(+2/-1 for every match)
Total 20 88
CHEMISTRY:
Matrix Matching
Sec – III(Q.N : 39 – 40) 8 -4 2 16
Total 20 88
MATHEMATICS:
Matrix Matching
Sec – III(Q.N : 59 – 60) 8 -4 2 16
Total 20 88
Sec: Jr. Super60-I space for rough work Page 2
PHYSICS Max Marks: 88
SECTION – I
(SINGLE INTEGER ANSWER TYPE)
Marking scheme +4 for correct answer, 0 if not attempted and 0 in all other cases.
1. A circular tube of uniform cross-section is filled with two liquids of densities 1 and
 2 such that half of each liquid occupies a quarter of volume of the tube. If the line
joining the free surface of the liquids makes an angle  with horizontal, then
1  k12
tan   , where K1 and K2 is integer. Find the numerical value K1 / K2?
K 21  2
2. A wooden stick of length L, radius R and density  has a small metal piece of mass m
(of negligible volume) attached to its one end. The minimum value for the mass m (in
terms of given parameters) that would make the stick float vertically in equilibrium in
 
a liquid of density  is KR2L    1 . Find the value of K.
  
3. A cylinder of uniform cross-section is immersed into two liquids as shown in Fig.
Equal volume of cylinder is submerged in both the liquids and density of cylinder is .
The magnitude of acceleration of the cylinder at the shown instant is g/K. Where
equal volume of cylinder in two liquids. Find the value of K.
4. A liquid is kept in a cylindrical vessel which is rotated about its axis. The liquid rises
at the side. If the radius of the vessel is 0.05m and the speed of rotation is 2 rev/sec.
Find the difference in the height of the liquid at the centre of the vessel and its sides

(in cm). g  9.86m / s 2 

5. A spherical tank of 1.2 m radius is half filled with oil of relative density 0.8. If the
tank is given a horizontal acceleration of 10 m/s2, the maximum pressure at any point
on the tank is 2(100  X)100 Pascal. 

Find the value of X. g  10m / s 2 
6. A vessel contains two immiscible liquids of density 1 = 1000kg/m3 and 2 = 1500
kg/m3. A solid block of volume V = 10 3m3 and density d = 800 kg/m3 is tied to one
end of a string and the other is tied to the bottom of the vessel as shown in fig. The
block is immersed with 2/5th of its volume in the liquid of higher density and 3/5th in
the liquid of lower density. The entire system is kept in an elevator which is moving
upwards with an acceleration of a = g/2. Find the tension (in newtons) in the string.
(g = 10 m/s2)

7. A sphere is just immersed in a liquid. Find the ratio of hydrostatic force acting on
bottom half and top half of the sphere.
8. The vertical limbs of a U shaped tube are filled with a liquid of density upto a height
h on each side. The horizontal portion of the U tube having length 2h contains a liquid
of density 2. The U tube is moved horizontally with an accelerator g/2 parallel to the
horizontal arm. The difference in heights in liquid levels in the two vertical limbs, at
nh
steady state is Find n.
7
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
answer, out of which ONE OR MORE than ONE option can be correct.
9. A solid completely immersed in a liquid. The force exerted by the liquid on the solid
will
A) Increase if it is pushed deeper inside the liquid
B) Change if its orientation is changed
C) Decrease if it is taken partially out of the liquid
D) Be in the vertically upward direction.
10. The vessel shown in the figure has two sections. The lower part is a rectangular
vessel with area of cross-section A and height h. The upper part is a conical vessel of
height h with base area ‘A’ and top area ‘a’ and the walls of the vessel area inclined at
an angle 300 with the vertical. A liquid of density  fills both the sections upto a
height 2h. Neglecting atmospheric pressure (F= force exerted by the liquid on the
base of the vessel, w weight of liquid)
A) the force F exerted by the liquid on the base of the vessel is A  a

2hg
2
A
B) the pressure P at the base of the vessel is 2hgg
a
C) the weight of the liquid W is greater than the force exerted by the liquid on the base
D) the walls of the vessel exert a downward force (FW) on the liquid

11. The spring balance A reads 2 kg with a block suspended from it. A balance B reads
5 kg when a beaker with liquid is put on the pan of the balance. The two balances are
now so arranged that the hanging mass is inside the liquid in the beaker as shown in
Fig. In this situation:
A) the balance A will read more than 2 kg

B) the balance B will read more than 5 kg
C) the balance A will read less than 2 kg and B will read more than 5 kg
D) the balances A and B will read 2 kg and 5 kgrespectivel

12. A liquid is filled up to height h in a vessel, as shown. Find correct (s);
A) If    , horizontal component of forces on left and right side of inclined faces

will be equal and opposite.
B) If    , horizontal component of forces on left and right side of inclined faces will
be equal and opposite.
C) If A is the area of the base of the vessel, then force exerted by liquid on walls of
the vessel is greater than  Patm   gh  A
D) As above, the force exerted by liquid on walls is equal to  Patm   gh  A

13. A bottle is kept on the ground as shown in the figure. The bottle can be modeled as
having two cylindrical zones. The lower zone of the bottle has a cross-sectional radius
of R 2 and is filled with honey of density 2. The upper zone of the bottle is filled
with the water of density  and has a cross-sectional radius R . The height of the lower

zone is H while that of the upper zone is 2H . If now the honey and the water parts
are mixed together to form a homogeneous solution: (Assume that total volume does
not change)
A) The pressure inside the bottle at the base will remain unaltered
B) The normal reaction on the bottle form the ground will remain unaltered
C) The pressure inside the bottle at the base will increase by an amount (1/2) gH
D) The pressure inside the bottle at the base will decrease by an amount (1/4) gH

14. The vessel shown in the Fig. has two sections of areas of cross-section A1 and A2. A
liquid of density  fills both the sections, up to a height h in each. Neglect
atmospheric pressure.
A) the pressure at the base of the vessel is 2hg

B) the force exerted by the liquid on the base of the vessel is 2hgA2
C) the weight of the liquid is < 2hgA2
D) the walls of the vessel at the level X exert a downward force hg(A2 A1)on the
liquid
15. A solid sphere of mass m, is suspended by means of a string in a liquid as shown. The
string has some tension. Magnitudes of net force due to liquid on upper hemisphere

and that on lower hemisphere are FA and FB respectively.Which of the following is/are
true.
A) Density of material of the sphere is greater than density of liquid

B) Difference of FB and FA is dependent of atmospheric pressure
C) FB-FA=mg
D) FB-FA<mg
16. When a body is weighed in a liquid, the loss in its weight is equal to:
A) weight of liquid displaced by the body
B) weight of water displaced by the body
C) the difference in weights of body in air and liquid
D) the up thrust of liquid on the body
17. An iron block and a wooden block are positioned in a vessel containing water as
shown in the figure. The iron block (I) hangs from a massless string with a rigid
support from the top while the wooden block floats being tied to the bottom through a
massless string. If now the vessel starts accelerating upwards
A) tension in the string 1 will increase.

B) tension in both the strings will increase.
C) tension in both the strings will decrease.
D) tension in the string 2 will remain constant.
18. A piece of ice is floating in a liquid( water soluble liquid) in a container. What
happens to the level of liquid when all ice melts?
A) Level remains same if liquid is water
B) Level will fall if liquid is water
C) Level will rise if liquid is denser than water
D) Level will rise if liquid is lighter than water
SECTION - III
(MATRIX MATCHING ANSWER TYPE)
This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R
and S) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question
darken the bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +2 marks ONLY and
0 if not attempted and -1 in all other cases.
19. Match the following columns
Bucket A contains only water, an identical bucket B contains water, but also contains
a solid object in the water. Match the Column-I with Column-II.
(A) The object floats in bucket B, and the
(P) Bucket A has more weight.
buckets have the same water level.
(B) The object floats in bucket B and the
(Q) Both buckets have the same weight.
buckets have the same volume of water.
(C) The object sinks completely in
buckets B, and the buckets have the same (R) Bucket B has more weight.
water level.
(D) The object sinks completely in bucket
(S) The answer cannot be determined
B, and the buckets have the same volume
from the information given.
of water.
20. Match the following columns ( liquid is non viscous)
  
(A) A cube of mass m and density  is pulled by a force F x  mg i in an (P)

ax
accelerating liquid of density . The value of is
ay
(   , ax , a y with respect to ground)
(B) The sphere of mass m is pulled horizontally (Q) 1 : 1

by a force Fx = mg in a non accelerating liquid.
ax
The value of is (   )
ay
(C) A solid cube of side X is placed in a tube of (R) 


rotating liquid such that its closer surface is at a distance of X from the

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Sec: Jr.Super60-I Page 2

Water soluble Insoluble

C) Due to steric hindrance in 2,6-dimethyl pyridine.

Sec: Jr.Super60-I Page 4

c) Na2O  2H 2O  2 NaOH ;NaOH being basic turns red litmus blue.

agent bleaches coloured litmus.

23. The different forces on the block are shown in figure.

From (1),(2) and (3),

Sec: Jr.Super60-I Page 6

Balancing all torque about point A, we use

Sec: Jr.Super60-I Page 7

Sec: Jr.Super60-I Page 8

34. Just after the thread is burnt

35. Torque equation (discus)

Sec: Jr.Super60-I Page 9

Sec: Jr.Super60-I Page 10

(Remembering terms in two braces are reciprocal of each other)

Sec: Jr.Super60-I Page 11

 1  x 1  2 x 1  3 x 1  4 x 1/4  1 

Sec: Jr.Super60-I Page 12

If f 1  1, Then 2  f  x 1  f  x   1  f  x 

f  x   1  x 2 which is a continuous function

Sec: Jr.Super60-I Page 13

Sec: Jr.Super60-I Page 14

Taking ln both sides, ln k

Sec: Jr.Super60-I Page 15

On comparing, we have –a=b

Also lim f  x   lim x cot x  cot1 ……2

Sec: Jr.Super60-I Page 16

Sec: Jr.Super60-I Page 17

99  1  100h   1 100h  1 as h  0

Sec: Jr.Super60-I Page 18

Sec: Jr.Super60-I Page 19

Sri Chaitanya IIT Academy., India.

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30

Sec: Jr. Super60-I space for rough work 2

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

Sec: Jr. Super60-I space for rough work 3

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

between them is 0.3. The board is imparted a constant acceleration of a 6m / s 2 in a

Sec: Jr. Super60-I space for rough work 4

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

A) The acceleration of the cylinder axis in the absence of slipping

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

speed VB t where t is time in s. Choose the correct choice (s) at time t 0 .

A) Angular acceleration of rod is 2 rad / s 2

Sec: Jr. Super60-I space for rough work 6

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

A) LO and LP do not vary with time

Sec: Jr. Super60-I space for rough work 7

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

Sec: Jr. Super60-I space for rough work 8

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

Sec: Jr. Super60-I space for rough work 9

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

pure rolling down the plane will start.

time will be 2mg sin .

Sec: Jr. Super60-I space for rough work 10

Sri Chaitanya IIT Academy 23-09-17_Jr.Super60-I_JEE-ADV_2014_P1_WAT-19_Q’P

A) If tan , the wedge will not topple for any value of m.