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Narayana IIT Academy

INDIA
Sec: XII-IIT-CF Date: 29-08-2021
Time: 02:00 PM to 05:00 PM Max. Marks:186

2016_PAPER-II
29-08-2021_XII-IIT-CF_PTA-04_[PHASE TEST]
MATHS: PT-4 Syllabus PHYSICS: PT-4 Syllabus CHEMISTRY: PT-4 Syllabus
IMPORTANT INSTRUCTIONS
PHYSICS:
+Ve -Ve No. of Total
Question Type
Section Marks Marks Qs marks
Sec – I(Q.N : 1 – 6) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct Choice
Sec – II(Q.N : 7 – 14) 4 -2 8 32
(Partial Marking +1)
Questions with Comprehension Type
Sec – III(Q.N : 15 – 18) 3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 62
CHEMISTRY:
+Ve -Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 24) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct Choice
Sec – II(Q.N : 25 – 32) 4 -2 8 32
(Partial Marking +1)
Questions with Comprehension Type
Sec – III(Q.N : 33 – 36) 3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 62
MATHEMATICS:
+Ve -Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 42) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct Choice
Sec – II(Q.N : 43 – 50) 4 -2 8 32
(Partial Marking +1)
Questions with Comprehension Type
Sec – III(Q.N : 51 – 54) 3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 62
NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. In the circuit shown in figure ammeter and voltmeter are ideal. If E = 4 V, R = 9 Ω and r = 1 Ω, then
readings of ammeter and voltmeter are

(A) 1 A, 3V (B) 2 A, 3V (C) 3 A, 4V (D) 4 A, 4 V


2. A uniform current carrying ring of mass m and radius R is connected by a massless string as shown. A
uniform magnetic field B0 exist in the region to keep the ring in horizontal position, then the current in
the ring is

mg mg mg mg
(A) (B) (C) (D)
π RB0 RB0 3π RB0 π R 2 B0
3. A long straight wire AB carries a current of 4A. A proton P travels at 4 × 106 ms-1 parallel to the wire,
0.2 m from it and in a direction opposite to the current as shown Calculate the force which the
magnetic field of current exerts on the proton. Also specify the direction of force.
A

B
-18
(A) 2.56 × 10 N towards left (B) 2.56 × 10-18N towards right
(C) 5.12 × 10-18N towards left (D) 5.12 × 10-18N towards right
4. A conducting rod is moving with a constant velocity v over the parallel conducting rails which are
connected at the ends through a resister R and Capacitor C as shown in the figure. Magnetic field B is
into the plane. Consider the following statements.

(i) Current in loop AEFBA is anti-clockwise (ii) Current in loop AEFBA is clockwise
1
(iii) Current through the capacitor is zero (iv) Energy stored in the capacitor is CB 2 L2 v 2
2
Which of the following options is correct?

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
(A) Statement (i) and (iii) are correct
(B) Statements (ii) and (iv) are correct
(C) Statements (i), (iii) and (iv) are correct
(D) None of these
5. In a house there are four bulbs each of 50 W and 5 fans each of 60W. If they are used at the rate of 6
hours a day, the electrical energy consumed in a month of 30 days is
(A) 64 KWH (B) 90 KWH (C) 72 KWH (D) 42 KWH
6. Two point charges ‘Q’ and ‘2Q’ are placed at a distance ‘d’ on equatorial line of dipole of dipole
moment ‘p’ as shown in diagram. Find net force acting on the dipole due to point charges.
(where d >> size of dipole)

kpQ 3kpQ kpQ


(A) 0 (B) (C) (D) 5
d3 d3 d3

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases
7. Magnetic field in a cylindrical region of radius R in inward direction is as shown in figure.

(A) An electron will experience no force kept at (2R, 0,0) if magnetic field increase with time.
(B) In the above situation, electron will experience the force in negative y-axis.
 R 
(C) If a proton is kept at  0, ,0  and magnetic field is decreasing, then it will experience the force
 2 
positive x-direction.
(D) If a proton is kept at (-R, 0, 0) and magnetic field is increasing, then it will experience force in
negative y-axis.
8. Two concentric shells have radii R and 2R charges q A and qB and potentials 2V and (3/2) V
respectively. Now shell B is earthed and let charges on them become q ′A and q′B . Then

(A) q A / qB = 1/ 2 (B) q′A / q′B = 1


(C) potential of A after earthing becomes (3/2) V
(D) potential difference between A and B after earthing become V/2.
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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
9. A few electric field lines for a system of two charges Q1 and Q2 fixed at two different points on the x-
axis are shown in the figure. These lines suggest that :

(A) | Q1 |>| Q2 |
(B) | Q1 |<| Q2 |
(C) at a finite distance to the left of Q1 the electric field is zero
(D) at a finite distance to the right of Q2 the electric field is zero
10. A flat circular coil, carrying a current, has a magnetic moment µ
(A) µ has only magnitude; it does not have direction
(B) The direction of µ is along the normal to the plane of the coil
(C) The direction of µ depends on the direction of the current flows
(D) The direction of µ does not change if the current in the coil is reversed
11. An equilateral triangular conducting frame is rotated with angular velocity ω in a uniform magnetic
field B as shown. Side of triangle is l. Choose the correct options.

Bωl 2 Bωl 2 Bωl 2


(A) Va − Vc = 0 (B) Va − Vc = (C) Va − Vb = (D) Vc − Vb = −
2 2 2
12. In a potentiometer experiment, the balancing length with a cell is 560 cm. When an external resistance
of 10 ohms is connected in parallel to the cell the balancing length changes by 60cm. The internal
resistance of the cell in ohm is
(A) 3.6 (B) 2.4 (C) 1.2 (D) 0.6
13. In a parallel plate capacitor, the potential difference between the plates is V. A particle of mass m and
charge –Q leaves the negative plate and reaches the positive plate at distance d in time with a
momentum p. Then (neglect gravity)
md 2 2md 2
(A) p = mQV (B) p = 2mQV (C) t = (D) t =
QV QV
14. Two circular coils of radii 5 cm and 10 cm carry currents of 2 A. The coils have 50 and 100 turns
respectively and are placed in such a way that their planes as well as their centres coincide. Magnitude
of magnetic field at the common centre of coils is
(A) 8π × 10 −4 T if currents in the coils are in same sense.
(B) 4π ×10 −4 T if currents in the coils are in same sense.
(C) zero if currents in the coils are in opposite sense
(D) 8π × 10 −4 T if currents in the coils are in opposite sense.

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 15 and 16
A solid metallic sphere of radius a is surrounded by a conducting spherical shell of radius b (b > a).
The solid sphere is given a charge Q. A student measures the potential at the surface of the solid sphere as Va
and the potential at the surface of spherical shell as Vb . After taking these readings, he decides to put charge of
–4Q on the shell. He then noted the readings of the potential of solid sphere and the shell and found that the
potential difference is ∆V. He then connected the outer spherical shell to the earth by a conducting wire and
found that the charge on the outer surface of the shell as q1 .
He then decides to remove the earthing connection from the shell and earthed the inner solid sphere.
Connecting the inner sphere with the earth he observes the charge on the solid sphere as q2 . He then wanted to
check what happens if the two are connected by the conducting wire. So he removed the earthing connection
and connected a conducting wire between the solid sphere and the spherical shell. After the connections were
made he found the charge on the outer shell as q3 .
Answer the following questions based on the readings taken by the student at various stages.

15. Potential difference (∆V) measured by the student between the inner solid sphere and outer shell after
putting a charge –4Q is
(A) Va − 3Vb (B) 3(Va − Vb ) (C) Va (D) Va − Vb
16. q2 is
a
(A) Q (B) Q  (C) -4Q (D) zero
b
Paragraph for Questions 17 and 18
In the circuit shown at t < 0 the switch S is open and capacitor is uncharged.
The switch S is closed at t = 0. Then
B

3Ω 6Ω
A C
5µF

4Ω 4Ω S
D

36 Volts
17. The current through battery just after closing the switch is
(A) 6.75 A (B) 8.75 A (C) 2 A (D) 4 A
18. The charge on capacitor in steady state that is after a long time will be
(A) 30 µC (B) 20 µC (C) 25 µC (D) 35 µC

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19.

20. Monosaccharide and disaccharides are differentiate by


(A) Iodine test (B) Seliwanoff Test (C) Barfoed test (D) Tollen’s test
21. D-Galactose & D-Glucose are formed by the hydrolysis of following disaccharide.
(A) Sucrose (B) Lactose (C) Maltose (D) Amylose
22. Which of the following is the most stable enolate derived from 4-methylhexan-3-one?
O-
-
O- O-
O

(A) (B) (C) (D)


23. Consider the reactions :
+
X (C2H6O) →
Cu
A [  → Silver mirror observed
Ag ( NH3 )2 ]
573K

–OH, ∆ Y

O
||
NH2–NH–C–NH2 Z
Identify A, X, Y and Z.
(A) A–Ethanol, X–Acetaldehyde, Y–Butanone, Z-Hydrazone
(B) A–Methoxymethane, X–Ethanoic acid, Y–Acetate ion, Z–Hydrazine
(C) A–Methoxymethane, X–Ethanol, Y–Ethanoic acid, Z–Semicarbazide
(D) A–Ethanal, X–Ethanol Y–But-2-enal., Z–Semi carbazone
24. In the following reaction sequence, the correct structure(s) of X is (are)

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases
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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
25. Identify the intermediates of the following reaction
OH OH
CHO
+ CHCl3 + NaOH

O - -
O O O
H- H
CCl2 CHCl2 CCl3
(A) (B) (C) (D) CH2Cl

26. Silver mirror test is given by which one of the following compounds?
(A) Acetaldehyde (B) Acetone (C) Formaldehyde (D) Benzophenone
27. Identify the binary mixture(s) that can be separated into individual compounds by differential
extraction, as shown in the given scheme :

(A) C6 H 5OH and C6 H 5COOH (B) C6 H 5COOH and C6 H 5CH 2OH


(C) C6 H 5CH 2OH and C6 H 5OH (D) C6 H 5CH 2OH and C6 H 5CH 2COOH
28. Biuret test is given by
(A) carbohydrates (B) polypeptides (C) urea (D) proteins
29. Which of the following statements are correct for below reaction?
Br
CH2-CH3 CH-CH3

NBS

(A) Reaction intermediate is carbocation


(B) Product is mixture of two enantiomers
(C) Reaction intermediate is stabilized by +I, hyperconjugation & resonance
(D) Br2 at high temperature also give same product in the presence of NBS

30. With reference to the scheme given, which of the given statement(s) about T, U, V and W is(are)
correct?

(A) T is soluble in hot aqueous NaOH


(B) U is optically active
(C) Molecular formula of W is C10 H 18O4
(D) V gives effervescence on treatment with aqueous NaHCO3

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
31. The reaction that gives phenol is/are
+
(A) + Conc.H 2 SO4 → 
Heat
→ →
KOH H
Fusion H 2O

(B)  
NaNO2
0
→ →
KOH
HCl ; 0 C

0
(C) + KOH 300
 C
→ 
→
HCl

+ +
(D) + CH 3 − CH = CH 2 →
H
→
O2
→
H
KOH

32. Consider the following four compounds I, II, III, and IV.

Choose the correct statement(s)


(A) The order of basicity is II > I > III > IV.
(B) The magnitude of pK b difference between I and II is more than that between III and IV.
(C) Resonance effect is more in III than in IV.
(D) Steric effect makes compound IV more basic than III.

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 33 and 34
An organic acid P (C11H12O2) can easily be oxidized to a dibasic acid which reacts with ethylene glycol to
produce a polymer Dacron. Upon ozonolysis, P gives an aliphatic ketone as one of the products P. undergoes
the following reaction sequences to furnish R via. Q. The compound P also undergoes another set of reactions
to produce S.

(There are two questions based on PARAGRAPH ‘A’ the given below is one of them)
33. The compound R is

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
34. The compound S is

Paragraph for Questions 35 and 36


Treatment of compound O with KMnO4 / H + gave P, which on heating with ammonia gave Q. The compound
Q on treatment with Br2 / NaOH produced R. On strong heating, Q gave S, which on further treatment with
ethyl 2-bromopropanoate in the presence of KOH followed by acidification, gave a compound T.

35. The compound R is

36. The compound T is


(A) glycine (B) alanine (C) valine (D) serine

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
ln (1+ x )
1
∫ (1 − tan 2 y )
1/ y
37. lim dy equals :
x →0 sin x
0

(A) e −2 (B) e (C) e 2 (D) e 4


38. If y = y (x) and it follows the relation 4 xe = y + 5 sin x , then y′(0) is equal to
xy 2

(A) 2 (B) 4 (C) 6 (D) 8


2
x
39. If the function f ( x ) = c x.e − x − + x is decreasing for every − ∞ < x ≤ 0 , then the least value of c 2 is
2
equal to
(A) 1 (B) 2 (C) 3 (D) 4
40. If θ is acute angle of intersection of the curves x 2 + y 2 = 8 and x 2 = 2 y then θ equals :
π
(A) tan −1 2 (B) tan −1 3 (C) tan −1 1 (D)
2
41. The area enclosed by g(x), x = –3, x = 5 and x-axis where g(x) is the inverse of f ( x) = x3 + 3x + 1 is
5 7 9 11
(A) (B) (C) (D)
2 2 2 2
dx x 2009
42. If ∫ = f ( x ) + C1 and ∫ dx = g ( x) + C2 (where C1 and C 2 are constant of integration).
x + x 2011 1 + x 2010
Let h(x) = f(x) + g(x). If h(1) = 0 then h(e) is equal to
(A) 0 (B) 1 (C) e (D) 2

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases
43. Consider a differentiable function f : R → R for which f’(0)=ln 2 f and f ( x + y ) = 2 x f ( y ) + 4 y f ( x ),
∀ x, y ∈ R Which of the following is(are) correct?
(A) f (4) = 240 (B) f ′(2) = 24 ln 2
−1
(C) The minimum value of y = f ( x ) is (D) The number of solution of f(x) = 2 is l
4
x
44. Let f be a real valued function defined on R(the set of all real numbers) as f ( x ) = π   then which of
π 
the following is (are) correct? [Note : Where { . } denotes fractional part function.]
π
(A) Range of f(x) is [0,π) (B) lim f ( x ) =
π 2
x→
2

 5π 
∫ f (x )dx = π (D) f '   =1
2
(C)
0  2 
45. Let : f : [0, ∞ ) → A; f ( x ) = tan −1 x + π − tan −1 x is an onto function, then :
(A) f(x) is injective (B) f(x) is many – one
(C) set A is [ π , 2π ) (D) set A is [ π , 2 π )
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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04

Let f ( x ) = 1 + ln (c + c + 1) tan ( x − 1)(ln x ) , x ≠ 1 , where c ∈R


 2 2
1
2
46.
3c, x =1
If lim f ( x ) exists but f (x) is discontinuous at x = 1, then c can take the value :
x →1

(A) 1 (B) 2 (C) 3 (D) 4


 tan −1 ( x − 1), x ≤1
47. If f ( x ) =  3
a x + bx + c, x > 1
2

is non-derivable at exactly one point in R and f ′(2) = 0 , then


2
(A) a + b = (B) c – 2a = 0
3
f ( x ) − f (3) f ( x ) − f (− 3)
(C) lim = −3 (D) lim = −3
x→3 x−3 x → −3 x+3
( )
n
48. If S n = ∑ cot −1 r 2 + 3r + 3 , then
r =1

 17 
(A) S ∞ = cot −1 (2 ) (B) S 5 = cot −1 (3) (C) S 6 = cot −1   (D) S8 = cot −1 (5)
 6
π
49. Let a function f : R→R be defined as f (x) = x + sin x and I = ∫ f −1
(x )dx then :
0
1 1
1
(A) I > ∫ (B) I < ∫ e x dx
2
dx
0 1+ x
3
0

π π
(C) 2 < I < 3 (D) <I<
4 2
  −1  x 
tan x + 2 sgn  2 
, x≥0
50. Let f ( x ) =    1 + x   and g ( x ) = x + 2 − tan 1 ∀ x ∈ R .

 {[ x ] }, x<0
If h(x) = min.{f(x), g(x)}, then
(A) minimum value of h(x) is –tan 1.
(B) maximum value of h(x) is 3.
(C) number of points where h(x) is discontinuous is 2.
(D) number of points where h(x) is non-derivable is 5.
[Note : [y], {y} and sgn(y) denote greatest integer, fractional part and signum function of y
respectively.]
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 51 and 52
Let f : R→R be a continuous function satisfying f ( x ) = f (2 x ) ∀ x ∈ R. Also f(1) = 3.
51. The value of tan −1 (tan f ( x)) + sin −1 (sin f ( x)) + cos −1 (cos f ( x)) at x = 10, is equal to
(A) π (B) 6 – π (C) 3–π (D) 3
( )
1
52. The value of lim x 3 − tan 3 x − 2 + f ( x ) ( x5 ) is equal to
x→0
(A) e (B) 1/e (C) e2 (D) 1/e2
Paragraph for Questions 53 and 54

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NARAYANA IIT/NEET Academy 29-08-21_XII-IIT-CF_JEE-ADV_2016-P2_PTA-04
Let f (x) be a polynomial of degree 3 such that f (0) = 1, f (1) = 2 and zero is a critical point of f (x) having no
local extremum.
1
53. The value of lim( f ( x )) tan x − x is equal to
x →0

(A) e 2
(B) e −2 (C) e 3 (D) e −3
f (x )  a +1 
1
54. If the value of definite integral ∫ dx is equal to 2 ln  then the value of (a + b + c) is
−1 x2 + 7  b + c 
(A) 8 (B) 15 (C) 16 (D) 17

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